Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes
Authorized Users Only
2018
Authors
Živković, Emila
Živković, Nikola V.

Majstorović, Divna

Stanimirović, Andrej M.
Kijevčanin, Mirjana

Article (Published version)

Metadata
Show full item recordAbstract
This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analys...is of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models.
Keywords:
Density / Viscosity / Thermal conductivity / Refractive index / 1-Ethyl-3-methylimidazolium ethyl sulfate / ModelingSource:
Journal of Chemical Thermodynamics, 2018, 119, 135-154Publisher:
- Academic Press Ltd- Elsevier Science Ltd, London
Funding / projects:
- Research Fund of Ministry of Education, Science and Technological Development, Serbia
- New industrial and environmental application of chemical thermodynamics to the development of the chemical processes with multiphase and multicomponent systems (RS-172063)
DOI: 10.1016/j.jct.2017.12.023
ISSN: 0021-9614
WoS: 000425191700014
Scopus: 2-s2.0-85040376645
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Živković, Emila AU - Živković, Nikola V. AU - Majstorović, Divna AU - Stanimirović, Andrej M. AU - Kijevčanin, Mirjana PY - 2018 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3981 AB - This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models. PB - Academic Press Ltd- Elsevier Science Ltd, London T2 - Journal of Chemical Thermodynamics T1 - Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes EP - 154 SP - 135 VL - 119 DO - 10.1016/j.jct.2017.12.023 ER -
@article{ author = "Živković, Emila and Živković, Nikola V. and Majstorović, Divna and Stanimirović, Andrej M. and Kijevčanin, Mirjana", year = "2018", abstract = "This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models.", publisher = "Academic Press Ltd- Elsevier Science Ltd, London", journal = "Journal of Chemical Thermodynamics", title = "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes", pages = "154-135", volume = "119", doi = "10.1016/j.jct.2017.12.023" }
Živković, E., Živković, N. V., Majstorović, D., Stanimirović, A. M.,& Kijevčanin, M.. (2018). Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics Academic Press Ltd- Elsevier Science Ltd, London., 119, 135-154. https://doi.org/10.1016/j.jct.2017.12.023
Živković E, Živković NV, Majstorović D, Stanimirović AM, Kijevčanin M. Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2018;119:135-154. doi:10.1016/j.jct.2017.12.023 .
Živković, Emila, Živković, Nikola V., Majstorović, Divna, Stanimirović, Andrej M., Kijevčanin, Mirjana, "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 119 (2018):135-154, https://doi.org/10.1016/j.jct.2017.12.023 . .