The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the... change of one synthesis parameter was thereby demonstrated.
TY - JOUR
AU - Marković, Maja
AU - Spasojević, Pavle
AU - Šešlija, Sanja
AU - Popović, Ivanka
AU - Veljović, Đorđe
AU - Pjanović, Rada
AU - Panić, Vesna
PY - 2019
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4245
AB - The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - European Polymer Journal
T1 - Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties
EP - 288
SP - 276
VL - 113
DO - 10.1016/j.eurpolymj.2019.01.065
ER -
@article{
author = "Marković, Maja and Spasojević, Pavle and Šešlija, Sanja and Popović, Ivanka and Veljović, Đorđe and Pjanović, Rada and Panić, Vesna",
year = "2019",
abstract = "The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "European Polymer Journal",
title = "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties",
pages = "288-276",
volume = "113",
doi = "10.1016/j.eurpolymj.2019.01.065"
}
Marković, M., Spasojević, P., Šešlija, S., Popović, I., Veljović, Đ., Pjanović, R.,& Panić, V.. (2019). Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal
Pergamon-Elsevier Science Ltd, Oxford., 113, 276-288.
https://doi.org/10.1016/j.eurpolymj.2019.01.065
Marković M, Spasojević P, Šešlija S, Popović I, Veljović Đ, Pjanović R, Panić V. Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal. 2019;113:276-288.
doi:10.1016/j.eurpolymj.2019.01.065 .
