Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties
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2019
Authors
Marković, Maja
Spasojević, Pavle

Šešlija, Sanja

Popović, Ivanka

Veljović, Đorđe

Pjanović, Rada

Panić, Vesna

Article (Published version)

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The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the... change of one synthesis parameter was thereby demonstrated.
Keywords:
Casein / Hybrid polymer network / Poly(methacrylic acid) / Synthesis-structure-properties relationshipSource:
European Polymer Journal, 2019, 113, 276-288Publisher:
- Pergamon-Elsevier Science Ltd, Oxford
Funding / projects:
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
- Novel encapsulation and enzyme technologies for designing of new biocatalysts and biologically active compounds targeting enhancement of food quality, safety and competitiveness (RS-46010)
DOI: 10.1016/j.eurpolymj.2019.01.065
ISSN: 0014-3057
WoS: 000463979200032
Scopus: 2-s2.0-85060975410
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Tehnološko-metalurški fakultetTY - JOUR AU - Marković, Maja AU - Spasojević, Pavle AU - Šešlija, Sanja AU - Popović, Ivanka AU - Veljović, Đorđe AU - Pjanović, Rada AU - Panić, Vesna PY - 2019 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4245 AB - The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - European Polymer Journal T1 - Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties EP - 288 SP - 276 VL - 113 DO - 10.1016/j.eurpolymj.2019.01.065 ER -
@article{ author = "Marković, Maja and Spasojević, Pavle and Šešlija, Sanja and Popović, Ivanka and Veljović, Đorđe and Pjanović, Rada and Panić, Vesna", year = "2019", abstract = "The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "European Polymer Journal", title = "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties", pages = "288-276", volume = "113", doi = "10.1016/j.eurpolymj.2019.01.065" }
Marković, M., Spasojević, P., Šešlija, S., Popović, I., Veljović, Đ., Pjanović, R.,& Panić, V.. (2019). Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal Pergamon-Elsevier Science Ltd, Oxford., 113, 276-288. https://doi.org/10.1016/j.eurpolymj.2019.01.065
Marković M, Spasojević P, Šešlija S, Popović I, Veljović Đ, Pjanović R, Panić V. Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal. 2019;113:276-288. doi:10.1016/j.eurpolymj.2019.01.065 .
Marković, Maja, Spasojević, Pavle, Šešlija, Sanja, Popović, Ivanka, Veljović, Đorđe, Pjanović, Rada, Panić, Vesna, "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties" in European Polymer Journal, 113 (2019):276-288, https://doi.org/10.1016/j.eurpolymj.2019.01.065 . .