Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties
Samo za registrovane korisnike
2019
Autori
Marković, MajaSpasojević, Pavle
Šešlija, Sanja
Popović, Ivanka
Veljović, Đorđe
Pjanović, Rada
Panić, Vesna
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the... change of one synthesis parameter was thereby demonstrated.
Ključne reči:
Casein / Hybrid polymer network / Poly(methacrylic acid) / Synthesis-structure-properties relationshipIzvor:
European Polymer Journal, 2019, 113, 276-288Izdavač:
- Pergamon-Elsevier Science Ltd, Oxford
Finansiranje / projekti:
- Sinteza i karakterizacija novih funkcionalnih polimera i polimernih nanokompozita (RS-MESTD-Basic Research (BR or ON)-172062)
- Razvoj novih inkapsulacionih i enzimskih tehnologija za proizvodnju biokatalizatora i biološki aktivnih komponenata hrane u cilju povećanja njene konkurentnosti, kvaliteta i bezbednosti (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-46010)
DOI: 10.1016/j.eurpolymj.2019.01.065
ISSN: 0014-3057
WoS: 000463979200032
Scopus: 2-s2.0-85060975410
Kolekcije
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Marković, Maja AU - Spasojević, Pavle AU - Šešlija, Sanja AU - Popović, Ivanka AU - Veljović, Đorđe AU - Pjanović, Rada AU - Panić, Vesna PY - 2019 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4245 AB - The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - European Polymer Journal T1 - Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties EP - 288 SP - 276 VL - 113 DO - 10.1016/j.eurpolymj.2019.01.065 ER -
@article{ author = "Marković, Maja and Spasojević, Pavle and Šešlija, Sanja and Popović, Ivanka and Veljović, Đorđe and Pjanović, Rada and Panić, Vesna", year = "2019", abstract = "The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules-from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "European Polymer Journal", title = "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties", pages = "288-276", volume = "113", doi = "10.1016/j.eurpolymj.2019.01.065" }
Marković, M., Spasojević, P., Šešlija, S., Popović, I., Veljović, Đ., Pjanović, R.,& Panić, V.. (2019). Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal Pergamon-Elsevier Science Ltd, Oxford., 113, 276-288. https://doi.org/10.1016/j.eurpolymj.2019.01.065
Marković M, Spasojević P, Šešlija S, Popović I, Veljović Đ, Pjanović R, Panić V. Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal. 2019;113:276-288. doi:10.1016/j.eurpolymj.2019.01.065 .
Marković, Maja, Spasojević, Pavle, Šešlija, Sanja, Popović, Ivanka, Veljović, Đorđe, Pjanović, Rada, Panić, Vesna, "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties" in European Polymer Journal, 113 (2019):276-288, https://doi.org/10.1016/j.eurpolymj.2019.01.065 . .