Приказ основних података о документу

dc.creatorDespotović, Vesna
dc.creatorKordić, Branko
dc.creatorKovacević, M.
dc.creatorPetrović, Slobodan
dc.creatorJović, B.
dc.date.accessioned2021-03-10T14:11:11Z
dc.date.available2021-03-10T14:11:11Z
dc.date.issued2019
dc.identifier.issn0022-2860
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/4317
dc.description.abstractThis paper reports FT-IR and FT-NIR spectroscopic study of hydrogen bonding between N-mono-substituted caproamides and different ethers (diethyl ether and tetrahydrofuran) in carbon tetrachloride. With increase in ether concentration increase in intensity of red-shifted band, and decrease of intensity of monomer band has been observed. The MIR and NIR spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes and also the equilibrium constants for 1:1 complex formation are given. Further, influence of structural differences of ethers on hydrogen bonding was investigated using Taft equation. Good correlation between logarithm of formation constants and Taft steric and inductive factors has been obtained only for tetrahydrofuran in MIR range.en
dc.publisherElsevier Science Bv, Amsterdam
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS//
dc.rightsrestrictedAccess
dc.sourceJournal of Molecular Structure
dc.subjectN-monosubstituted caproamidesen
dc.subjectHydrogen bonden
dc.subjectEthersen
dc.subjectFT-IRen
dc.titleInvestigation of Nsingle bondH⋯O interactions in N-monosubstituted caproamide – Ether systems: FT–IR and FT–NIR spectroscopic studyen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage24
dc.citation.other1181: 19-24
dc.citation.rankM22
dc.citation.spage19
dc.citation.volume1181
dc.identifier.doi10.1016/j.molstruc.2018.12.081
dc.identifier.scopus2-s2.0-85059585636
dc.identifier.wos000458612300004
dc.type.versionpublishedVersion


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Приказ основних података о документу