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Alumina/silica aerogel with zinc chloride alkylation catalyst: Influence of supercritical drying conditions and aerogel structure on alkylation catalytic activity

Authorized Users Only
2002
Authors
Orlović, Aleksandar
Janaćković, Đorđe
Skala, Dejan
Article (Published version)
Metadata
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Abstract
Alumina/silica aerogel with zinc chloride alkylation catalyst, was obtained using one step sol-gel synthesis and subsequent drying with the supercritical carbon dioxide. The high density supercritical carbon dioxide drying conditions resulted in zinc chloride removal from the catalyst surface, surface area and pore volume increase and catalytic activity decrease. The low density supercritical carbon dioxide drying conditions, pore size distribution centred around 6 nm pore radius and high degree of mixed Al-O-Si bonds in the alumina/silica aerogel network, were found to increase the catalytic activity of the obtained aerogel catalysts.
Keywords:
aerogel alkylation catalyst / sol-gel synthesis / zinc chloride / supercritical drying
Source:
Catalysis Communications, 2002, 3, 3, 119-123
Publisher:
  • Elsevier, Amsterdam

DOI: 10.1016/S1566-7367(02)00057-2

ISSN: 1566-7367

WoS: 000177695500005

Scopus: 2-s2.0-12144287307
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17
15
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/439
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Orlović, Aleksandar
AU  - Janaćković, Đorđe
AU  - Skala, Dejan
PY  - 2002
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/439
AB  - Alumina/silica aerogel with zinc chloride alkylation catalyst, was obtained using one step sol-gel synthesis and subsequent drying with the supercritical carbon dioxide. The high density supercritical carbon dioxide drying conditions resulted in zinc chloride removal from the catalyst surface, surface area and pore volume increase and catalytic activity decrease. The low density supercritical carbon dioxide drying conditions, pore size distribution centred around 6 nm pore radius and high degree of mixed Al-O-Si bonds in the alumina/silica aerogel network, were found to increase the catalytic activity of the obtained aerogel catalysts.
PB  - Elsevier, Amsterdam
T2  - Catalysis Communications
T1  - Alumina/silica aerogel with zinc chloride alkylation catalyst: Influence of supercritical drying conditions and aerogel structure on alkylation catalytic activity
EP  - 123
IS  - 3
SP  - 119
VL  - 3
DO  - 10.1016/S1566-7367(02)00057-2
ER  - 
@article{
author = "Orlović, Aleksandar and Janaćković, Đorđe and Skala, Dejan",
year = "2002",
abstract = "Alumina/silica aerogel with zinc chloride alkylation catalyst, was obtained using one step sol-gel synthesis and subsequent drying with the supercritical carbon dioxide. The high density supercritical carbon dioxide drying conditions resulted in zinc chloride removal from the catalyst surface, surface area and pore volume increase and catalytic activity decrease. The low density supercritical carbon dioxide drying conditions, pore size distribution centred around 6 nm pore radius and high degree of mixed Al-O-Si bonds in the alumina/silica aerogel network, were found to increase the catalytic activity of the obtained aerogel catalysts.",
publisher = "Elsevier, Amsterdam",
journal = "Catalysis Communications",
title = "Alumina/silica aerogel with zinc chloride alkylation catalyst: Influence of supercritical drying conditions and aerogel structure on alkylation catalytic activity",
pages = "123-119",
number = "3",
volume = "3",
doi = "10.1016/S1566-7367(02)00057-2"
}
Orlović, A., Janaćković, Đ.,& Skala, D.. (2002). Alumina/silica aerogel with zinc chloride alkylation catalyst: Influence of supercritical drying conditions and aerogel structure on alkylation catalytic activity. in Catalysis Communications
Elsevier, Amsterdam., 3(3), 119-123.
https://doi.org/10.1016/S1566-7367(02)00057-2
Orlović A, Janaćković Đ, Skala D. Alumina/silica aerogel with zinc chloride alkylation catalyst: Influence of supercritical drying conditions and aerogel structure on alkylation catalytic activity. in Catalysis Communications. 2002;3(3):119-123.
doi:10.1016/S1566-7367(02)00057-2 .
Orlović, Aleksandar, Janaćković, Đorđe, Skala, Dejan, "Alumina/silica aerogel with zinc chloride alkylation catalyst: Influence of supercritical drying conditions and aerogel structure on alkylation catalytic activity" in Catalysis Communications, 3, no. 3 (2002):119-123,
https://doi.org/10.1016/S1566-7367(02)00057-2 . .

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