Iron(III) phosphate-oxalate (FePO-DAP) crystallizes from a clear solution containing 1,2-diaminopropane (DAP) and oxalic acid at 120 degreesC under hydrothermal conditions. Doubly protonated DAP is present inside a large one-dimensional 12-membered channel in a disordered manner, its presence creating different environments for the Fe atoms situated across one another at the sides of the channel. This is evident by Mossbauer spectroscopy: the spectrum at 4.2 K exhibits two sextets with an identical isomer shift of about 0.42 mm/s. FePO-DAP undergoes magnetic ordering at a low temperature (19 K).
TY - JOUR
AU - Rajić, Nevenka
AU - Stojaković, D.
AU - Hanžel, Darko
AU - Zabukovec-Logar, Nataša
AU - Kaučič, Venčeslav
PY - 2002
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/446
AB - Iron(III) phosphate-oxalate (FePO-DAP) crystallizes from a clear solution containing 1,2-diaminopropane (DAP) and oxalic acid at 120 degreesC under hydrothermal conditions. Doubly protonated DAP is present inside a large one-dimensional 12-membered channel in a disordered manner, its presence creating different environments for the Fe atoms situated across one another at the sides of the channel. This is evident by Mossbauer spectroscopy: the spectrum at 4.2 K exhibits two sextets with an identical isomer shift of about 0.42 mm/s. FePO-DAP undergoes magnetic ordering at a low temperature (19 K).
PB - Elsevier, Amsterdam
T2 - Microporous and Mesoporous Materials
T1 - Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent
EP - 319
IS - 3
SP - 313
VL - 55
DO - 10.1016/S1387-1811(02)00434-1
ER -
@article{
author = "Rajić, Nevenka and Stojaković, D. and Hanžel, Darko and Zabukovec-Logar, Nataša and Kaučič, Venčeslav",
year = "2002",
abstract = "Iron(III) phosphate-oxalate (FePO-DAP) crystallizes from a clear solution containing 1,2-diaminopropane (DAP) and oxalic acid at 120 degreesC under hydrothermal conditions. Doubly protonated DAP is present inside a large one-dimensional 12-membered channel in a disordered manner, its presence creating different environments for the Fe atoms situated across one another at the sides of the channel. This is evident by Mossbauer spectroscopy: the spectrum at 4.2 K exhibits two sextets with an identical isomer shift of about 0.42 mm/s. FePO-DAP undergoes magnetic ordering at a low temperature (19 K).",
publisher = "Elsevier, Amsterdam",
journal = "Microporous and Mesoporous Materials",
title = "Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent",
pages = "319-313",
number = "3",
volume = "55",
doi = "10.1016/S1387-1811(02)00434-1"
}
Rajić, N., Stojaković, D., Hanžel, D., Zabukovec-Logar, N.,& Kaučič, V.. (2002). Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent. in Microporous and Mesoporous Materials
Elsevier, Amsterdam., 55(3), 313-319.
https://doi.org/10.1016/S1387-1811(02)00434-1
Rajić N, Stojaković D, Hanžel D, Zabukovec-Logar N, Kaučič V. Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent. in Microporous and Mesoporous Materials. 2002;55(3):313-319.
doi:10.1016/S1387-1811(02)00434-1 .
Rajić, Nevenka, Stojaković, D., Hanžel, Darko, Zabukovec-Logar, Nataša, Kaučič, Venčeslav, "Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent" in Microporous and Mesoporous Materials, 55, no. 3 (2002):313-319,
https://doi.org/10.1016/S1387-1811(02)00434-1 . .
