Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent
Samo za registrovane korisnike
2002
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Iron(III) phosphate-oxalate (FePO-DAP) crystallizes from a clear solution containing 1,2-diaminopropane (DAP) and oxalic acid at 120 degreesC under hydrothermal conditions. Doubly protonated DAP is present inside a large one-dimensional 12-membered channel in a disordered manner, its presence creating different environments for the Fe atoms situated across one another at the sides of the channel. This is evident by Mossbauer spectroscopy: the spectrum at 4.2 K exhibits two sextets with an identical isomer shift of about 0.42 mm/s. FePO-DAP undergoes magnetic ordering at a low temperature (19 K).
Ključne reči:
iron-phosphate / open-framework / hydrothermal synthesis / inorganic-organic hybrid / Mossbauer spectroscopyIzvor:
Microporous and Mesoporous Materials, 2002, 55, 3, 313-319Izdavač:
- Elsevier, Amsterdam
DOI: 10.1016/S1387-1811(02)00434-1
ISSN: 1387-1811
WoS: 000178419900009
Scopus: 2-s2.0-0037201341
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Rajić, Nevenka AU - Stojaković, D. AU - Hanžel, Darko AU - Zabukovec-Logar, Nataša AU - Kaučič, Venčeslav PY - 2002 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/446 AB - Iron(III) phosphate-oxalate (FePO-DAP) crystallizes from a clear solution containing 1,2-diaminopropane (DAP) and oxalic acid at 120 degreesC under hydrothermal conditions. Doubly protonated DAP is present inside a large one-dimensional 12-membered channel in a disordered manner, its presence creating different environments for the Fe atoms situated across one another at the sides of the channel. This is evident by Mossbauer spectroscopy: the spectrum at 4.2 K exhibits two sextets with an identical isomer shift of about 0.42 mm/s. FePO-DAP undergoes magnetic ordering at a low temperature (19 K). PB - Elsevier, Amsterdam T2 - Microporous and Mesoporous Materials T1 - Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent EP - 319 IS - 3 SP - 313 VL - 55 DO - 10.1016/S1387-1811(02)00434-1 ER -
@article{ author = "Rajić, Nevenka and Stojaković, D. and Hanžel, Darko and Zabukovec-Logar, Nataša and Kaučič, Venčeslav", year = "2002", abstract = "Iron(III) phosphate-oxalate (FePO-DAP) crystallizes from a clear solution containing 1,2-diaminopropane (DAP) and oxalic acid at 120 degreesC under hydrothermal conditions. Doubly protonated DAP is present inside a large one-dimensional 12-membered channel in a disordered manner, its presence creating different environments for the Fe atoms situated across one another at the sides of the channel. This is evident by Mossbauer spectroscopy: the spectrum at 4.2 K exhibits two sextets with an identical isomer shift of about 0.42 mm/s. FePO-DAP undergoes magnetic ordering at a low temperature (19 K).", publisher = "Elsevier, Amsterdam", journal = "Microporous and Mesoporous Materials", title = "Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent", pages = "319-313", number = "3", volume = "55", doi = "10.1016/S1387-1811(02)00434-1" }
Rajić, N., Stojaković, D., Hanžel, D., Zabukovec-Logar, N.,& Kaučič, V.. (2002). Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent. in Microporous and Mesoporous Materials Elsevier, Amsterdam., 55(3), 313-319. https://doi.org/10.1016/S1387-1811(02)00434-1
Rajić N, Stojaković D, Hanžel D, Zabukovec-Logar N, Kaučič V. Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent. in Microporous and Mesoporous Materials. 2002;55(3):313-319. doi:10.1016/S1387-1811(02)00434-1 .
Rajić, Nevenka, Stojaković, D., Hanžel, Darko, Zabukovec-Logar, Nataša, Kaučič, Venčeslav, "Preparation and characterization of iron(III) phosphate-oxalate using 1,2-diaminopropane as the structure-directing agent" in Microporous and Mesoporous Materials, 55, no. 3 (2002):313-319, https://doi.org/10.1016/S1387-1811(02)00434-1 . .