Novel highly effective amino-functionalized lignin-based biosorbent in the microsphere geometry (A-LMS) for removal of heavy metal ions, was synthesized via inverse suspension copolymerization of kraft lignin with poly(ethylene imine) grafting-agent and epoxy chloropropane cross-linker. Optimization of A-LMS synthesis, performed with respect to the quantity of sodium alginate emulsifier (1, 5 and 10 wt%), provides highly porous microspheres A-LMS_5, using 5 wt% emulsifier, with 800 +/- 80 mu m diameter, 7.68 m(2) g(-1) surface area and 7.7 mmol g(-1) of terminal amino groups. Structural and surface characteristics were obtained from Brunauer-Emmett-Teller method, Fourier Transform-Infrared spectroscopy, scanning electron microscopy, X-ray photo-electron spectroscopy and porosity determination. In a batch test, the influence of pH, A-LMS_5 dose, temperature, contact time on adsorption efficiency of Ni2+, Cd2+, As(V) and Cr(VI) ions were studied. The adsorption is spontaneous and feasibl...e with maximum adsorption capacity of 74.84, 54.20, 53.12 and 49.42 mg g(-1) for Cd2+, Cr(VI), As(V) and Ni2+ ions, respectively, obtained by using Langmuir model. Modeling of kinetic data indicated fast adsorbate removal rate with pore diffusional transport as rate limiting step (pseudo-second order model and Weber-Morris equations), thus further confirming high performances of produced bio-adsorbent for heavy metal ions removal.
Keywords:
lignin / Microspheres / Biosorbent
Source:
International Journal of Biological Macromolecules, 2020, 156, 1160-1173
Publisher:
Elsevier, Amsterdam
Funding / projects:
COST (European Cooperation in Science and Technology)European Cooperation in Science and Technology (COST) [CA17128]
TY - JOUR
AU - Popović, Ana L.
AU - Rusmirović, Jelena
AU - Veličković, Zlate
AU - Radovanović, Željko
AU - Ristić, Mirjana
AU - Pavlović, Vera P.
AU - Marinković, Aleksandar
PY - 2020
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4540
AB - Novel highly effective amino-functionalized lignin-based biosorbent in the microsphere geometry (A-LMS) for removal of heavy metal ions, was synthesized via inverse suspension copolymerization of kraft lignin with poly(ethylene imine) grafting-agent and epoxy chloropropane cross-linker. Optimization of A-LMS synthesis, performed with respect to the quantity of sodium alginate emulsifier (1, 5 and 10 wt%), provides highly porous microspheres A-LMS_5, using 5 wt% emulsifier, with 800 +/- 80 mu m diameter, 7.68 m(2) g(-1) surface area and 7.7 mmol g(-1) of terminal amino groups. Structural and surface characteristics were obtained from Brunauer-Emmett-Teller method, Fourier Transform-Infrared spectroscopy, scanning electron microscopy, X-ray photo-electron spectroscopy and porosity determination. In a batch test, the influence of pH, A-LMS_5 dose, temperature, contact time on adsorption efficiency of Ni2+, Cd2+, As(V) and Cr(VI) ions were studied. The adsorption is spontaneous and feasible with maximum adsorption capacity of 74.84, 54.20, 53.12 and 49.42 mg g(-1) for Cd2+, Cr(VI), As(V) and Ni2+ ions, respectively, obtained by using Langmuir model. Modeling of kinetic data indicated fast adsorbate removal rate with pore diffusional transport as rate limiting step (pseudo-second order model and Weber-Morris equations), thus further confirming high performances of produced bio-adsorbent for heavy metal ions removal.
PB - Elsevier, Amsterdam
T2 - International Journal of Biological Macromolecules
T1 - Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal
EP - 1173
SP - 1160
VL - 156
DO - 10.1016/j.ijbiomac.2019.11.152
ER -
@article{
author = "Popović, Ana L. and Rusmirović, Jelena and Veličković, Zlate and Radovanović, Željko and Ristić, Mirjana and Pavlović, Vera P. and Marinković, Aleksandar",
year = "2020",
abstract = "Novel highly effective amino-functionalized lignin-based biosorbent in the microsphere geometry (A-LMS) for removal of heavy metal ions, was synthesized via inverse suspension copolymerization of kraft lignin with poly(ethylene imine) grafting-agent and epoxy chloropropane cross-linker. Optimization of A-LMS synthesis, performed with respect to the quantity of sodium alginate emulsifier (1, 5 and 10 wt%), provides highly porous microspheres A-LMS_5, using 5 wt% emulsifier, with 800 +/- 80 mu m diameter, 7.68 m(2) g(-1) surface area and 7.7 mmol g(-1) of terminal amino groups. Structural and surface characteristics were obtained from Brunauer-Emmett-Teller method, Fourier Transform-Infrared spectroscopy, scanning electron microscopy, X-ray photo-electron spectroscopy and porosity determination. In a batch test, the influence of pH, A-LMS_5 dose, temperature, contact time on adsorption efficiency of Ni2+, Cd2+, As(V) and Cr(VI) ions were studied. The adsorption is spontaneous and feasible with maximum adsorption capacity of 74.84, 54.20, 53.12 and 49.42 mg g(-1) for Cd2+, Cr(VI), As(V) and Ni2+ ions, respectively, obtained by using Langmuir model. Modeling of kinetic data indicated fast adsorbate removal rate with pore diffusional transport as rate limiting step (pseudo-second order model and Weber-Morris equations), thus further confirming high performances of produced bio-adsorbent for heavy metal ions removal.",
publisher = "Elsevier, Amsterdam",
journal = "International Journal of Biological Macromolecules",
title = "Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal",
pages = "1173-1160",
volume = "156",
doi = "10.1016/j.ijbiomac.2019.11.152"
}
Popović, A. L., Rusmirović, J., Veličković, Z., Radovanović, Ž., Ristić, M., Pavlović, V. P.,& Marinković, A.. (2020). Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal. in International Journal of Biological Macromolecules
Elsevier, Amsterdam., 156, 1160-1173.
https://doi.org/10.1016/j.ijbiomac.2019.11.152
Popović AL, Rusmirović J, Veličković Z, Radovanović Ž, Ristić M, Pavlović VP, Marinković A. Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal. in International Journal of Biological Macromolecules. 2020;156:1160-1173.
doi:10.1016/j.ijbiomac.2019.11.152 .
Popović, Ana L., Rusmirović, Jelena, Veličković, Zlate, Radovanović, Željko, Ristić, Mirjana, Pavlović, Vera P., Marinković, Aleksandar, "Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal" in International Journal of Biological Macromolecules, 156 (2020):1160-1173,
https://doi.org/10.1016/j.ijbiomac.2019.11.152 . .
