The application of differential thermogravimetric analysis (DTGA) to the study of polymerization mechanisms is illustrated using as examples the radical polymerization of di‐n‐alkyl itaconates and methyl methacrylate (MMA). Five poly(di‐n‐alkyl itaconates) were prepared in bulk, both in the presence and absence of n‐dodecyl mercaptan and in solution using AIBN as initiator. The poly(methyl methacrylate) (PMMA) was photoinitiated using colloidal CdS as a photosensitizer. The thermal properties of the resulting polymers are described in terms of the proposed polymerization mechanisms. The advantages and disadvantages of DTGA for the identification of thermally weak structures are discussed.
Source:
Journal of Applied Polymer Science, 1993, 50, 8, 1475-1482
TY - JOUR
AU - Popović, Ivanka
AU - Katsikas, Lynne
AU - Weller, Horst
AU - Schrötter, S.
AU - Veličković, Jovan S.
PY - 1993
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/46
AB - The application of differential thermogravimetric analysis (DTGA) to the study of polymerization mechanisms is illustrated using as examples the radical polymerization of di‐n‐alkyl itaconates and methyl methacrylate (MMA). Five poly(di‐n‐alkyl itaconates) were prepared in bulk, both in the presence and absence of n‐dodecyl mercaptan and in solution using AIBN as initiator. The poly(methyl methacrylate) (PMMA) was photoinitiated using colloidal CdS as a photosensitizer. The thermal properties of the resulting polymers are described in terms of the proposed polymerization mechanisms. The advantages and disadvantages of DTGA for the identification of thermally weak structures are discussed.
PB - Wiley, Hoboken
T2 - Journal of Applied Polymer Science
T1 - Polymerization studies: The application of differential thermogravimetric analysis
EP - 1482
IS - 8
SP - 1475
VL - 50
DO - 10.1002/app.1993.070500819
ER -
@article{
author = "Popović, Ivanka and Katsikas, Lynne and Weller, Horst and Schrötter, S. and Veličković, Jovan S.",
year = "1993",
abstract = "The application of differential thermogravimetric analysis (DTGA) to the study of polymerization mechanisms is illustrated using as examples the radical polymerization of di‐n‐alkyl itaconates and methyl methacrylate (MMA). Five poly(di‐n‐alkyl itaconates) were prepared in bulk, both in the presence and absence of n‐dodecyl mercaptan and in solution using AIBN as initiator. The poly(methyl methacrylate) (PMMA) was photoinitiated using colloidal CdS as a photosensitizer. The thermal properties of the resulting polymers are described in terms of the proposed polymerization mechanisms. The advantages and disadvantages of DTGA for the identification of thermally weak structures are discussed.",
publisher = "Wiley, Hoboken",
journal = "Journal of Applied Polymer Science",
title = "Polymerization studies: The application of differential thermogravimetric analysis",
pages = "1482-1475",
number = "8",
volume = "50",
doi = "10.1002/app.1993.070500819"
}
Popović, I., Katsikas, L., Weller, H., Schrötter, S.,& Veličković, J. S.. (1993). Polymerization studies: The application of differential thermogravimetric analysis. in Journal of Applied Polymer Science
Wiley, Hoboken., 50(8), 1475-1482.
https://doi.org/10.1002/app.1993.070500819
Popović I, Katsikas L, Weller H, Schrötter S, Veličković JS. Polymerization studies: The application of differential thermogravimetric analysis. in Journal of Applied Polymer Science. 1993;50(8):1475-1482.
doi:10.1002/app.1993.070500819 .
Popović, Ivanka, Katsikas, Lynne, Weller, Horst, Schrötter, S., Veličković, Jovan S., "Polymerization studies: The application of differential thermogravimetric analysis" in Journal of Applied Polymer Science, 50, no. 8 (1993):1475-1482,
https://doi.org/10.1002/app.1993.070500819 . .
