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Complexes of d-block elements with aromatic o,o- and n,n-donor ligands: synthesis, structure, properties and applications

dc.contributor.advisorRogan, Jelena
dc.contributor.otherDapčević, Aleksandra
dc.contributor.otherTodorović, Tamara
dc.creatorRadovanović, Lidija D.
dc.date.accessioned2021-03-10T15:15:28Z
dc.date.available2021-03-10T15:15:28Z
dc.date.issued2018
dc.identifier.urihttp://eteze.bg.ac.rs/application/showtheses?thesesId=6246
dc.identifier.urihttps://fedorabg.bg.ac.rs/fedora/get/o:18860/bdef:Content/download
dc.identifier.urihttp://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=50655759
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/4674
dc.description.abstractReakcijom izmene liganada različitim metodama sinteze dobijeno je 22 ternarna kompleksa elemenata d-bloka [Mn(II), Co(II), Ni(II), Cu(II) i Zn(II)] sa anjonima aromatičnih polikarboksilnih kiselina (ftalne, izoftalne, tereftalne i piromelitne) kao O,O-donorskim ligandima i aromatičnim N,N-donorskim ligandima kao što su 2,2'-dipiridilamin i 2,2'-bipirimidin. Trinaest kompleksa sintetisano je u monokristalnom obliku, dok su ostala jedinjenja mikrokristalna. Prema vrsti centralnog atoma, u obliku monokristala dobijeno je pet Mn(II)-, dva Co(II)-, jedan Ni(II)-, dva Cu(II)-, dva Zn(II)-kompleksa, kao i bimetalni Mn(II)–Cu(II)-kompleks...sr
dc.description.abstractA series of 22 d-block element complexes [Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)] containing anions of aromatic polycarboxylate acids (phthalic, isophthalic, terephthalic and pyromellic) as O,O-donor ligands and aromatic N,N-donor ligands such as 2,2'-dipyridylamine and 2,2'-bipyrimidine, has been obtained by ligand exchange reaction using different synthetic methods. Thirteen complexes were obtained as single crystals, while the others were microcrystalline powders. According to the type of central atom, five Mn(II), two Co(II), one Ni(II), two Cu(II), two Zn(II) complexes, and bimetallic Mn(II)–Cu(II) complex were synthesized in form of single crystals. The structures of these compounds were determined by single-crystal X-ray analysis. Structural properties of complexes were discussed in detail and compared...sr
dc.publisherUniverzitet u Beogradu, Tehnološko-metalurški fakultet
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45007/RS//
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectkompleksi elemenata d-blokasr
dc.subjectkristalne strukturesr
dc.subjectO,O-donorski ligandisr
dc.subjectN,N-donorski ligandisr
dc.subjectmagnetizamsr
dc.subjectfotoluminescencijasr
dc.subjectantimikrobna aktivnostsr
dc.subjectnanomaterijalisr
dc.subjectcomplexes of d-block elementsen
dc.subjectcrystal structuresen
dc.subjectO,O-donor ligandsen
dc.subjectN,N-donor ligandsen
dc.subjectmagnetismen
dc.subjectphotoluminescenceen
dc.subjectantimicrobial activityen
dc.subjectnanomaterialsen
dc.titleKompleksi elemenata d-bloka sa aromatičnim O,O- I N, N-donorskim ligandima: sinteza, struktura, svojstva i primenasr
dc.titleComplexes of d-block elements with aromatic o,o- and n,n-donor ligands: synthesis, structure, properties and applicationsen
dc.typedoctoralThesis
dc.rights.licenseBY-NC-ND
dc.identifier.fulltexthttp://TechnoRep.tmf.bg.ac.rs/bitstream/id/2201/4671.pdf
dc.identifier.rcubhttps://hdl.handle.net/21.15107/rcub_technorep_4674
dc.type.versionpublishedVersion


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