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dc.creatorMijatovic, Nevenka N.
dc.creatorTerzic, Anja M.
dc.creatorPezo, Lato L.
dc.creatorMilicic, Ljiljana R.
dc.creatorŽivojinović, Dragana
dc.date.accessioned2022-03-04T11:13:41Z
dc.date.available2022-03-04T11:13:41Z
dc.date.issued2020
dc.identifier.issn0352-5139
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/4747
dc.description.abstractA modification of an analytical procedure for the energy-dispersive X-ray fluorescence (EDXRF) quantification of ten chemical elements (As, Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb and Zn) in the leachates obtained from cement binders was developed. Twenty-nine testing samples were used in the experiment. All samples were based on Portland cement. Fly ash of different origin, zeolite and bentonite were employed as mineral additives in the cement binders. Distilled water was used as the leachate. Validation of the modified EDXRF procedure was conducted in terms of limits of detection and quantification, working range, linearity, selectivity, precision, trueness, and robustness. Traceability of the procedure was established using certified reference materials. Uncertainty of measurement was confirmed via an "in-house" laboratory validation approach. The expanded uncertainties for the ten analysed elements were obtained for the entire working range of the EDXRF method. Robustness of the modified EDXRF procedure was assessed by means of a chemometric in-house approach. The results obtained by the modified X-ray fluorescence method were additionally correlated to those acquired by inductively coupled plasma optical emission spectrometry to confirm that EDXRF could be used as an effective and reliable alternative method for analysis of cement leachates.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200012/RS//
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceJournal of the Serbian Chemical Society
dc.subjectin-house validationen
dc.subjectmineral additivesen
dc.subjectcluster analysisen
dc.subjectICP-OESen
dc.subjectEDXRFen
dc.subjectbuilding materialsen
dc.titleImprovement and modification of the energy-dispersive X-ray fluorescence method for the determination of metal elements in cement leachates - A chemometric approachen
dc.typearticle
dc.rights.licenseBY-NC-ND
dc.citation.epage1619
dc.citation.issue12
dc.citation.other85(12): 1605-1619
dc.citation.rankM23
dc.citation.spage1605
dc.citation.volume85
dc.identifier.doi10.2298/JSC200501067M
dc.identifier.fulltexthttp://TechnoRep.tmf.bg.ac.rs/bitstream/id/7998/Improvement_and_modification_pub_2020.pdf
dc.identifier.scopus2-s2.0-85096893128
dc.identifier.wos000617343400007
dc.type.versionpublishedVersion


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Приказ основних података о документу