The preparation of poly(di-n-hexyl itaconate) (PDHI) in the presence of the chain transfer agent n-dodecyl mercaptan resulted in polymers of increased thermal stability, owing to the suppression of the number of chain terminal double bonds. The polymers were characterised by Fourier transform IR (FTIR) spectroscopy and gel permeation chromatography. The differential thermogravimetry (DTG) curves of all the PDHI samples had two peaks, showing that degradation occurred in two stages. The area of the lower-temperature DTG peak correlated with the number of terminal double bonds.
Source:
Polymer Degradation and Stability, 1993, 42, 3, 345-349
TY - JOUR
AU - Popović, Ivanka
AU - Katsikas, Lynne
AU - Voloschuk, K.A.
AU - Schrötter, S.
AU - Veličković, Jovan S.
PY - 1993
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/48
AB - The preparation of poly(di-n-hexyl itaconate) (PDHI) in the presence of the chain transfer agent n-dodecyl mercaptan resulted in polymers of increased thermal stability, owing to the suppression of the number of chain terminal double bonds. The polymers were characterised by Fourier transform IR (FTIR) spectroscopy and gel permeation chromatography. The differential thermogravimetry (DTG) curves of all the PDHI samples had two peaks, showing that degradation occurred in two stages. The area of the lower-temperature DTG peak correlated with the number of terminal double bonds.
PB - Elsevier Sci Ltd, Oxford
T2 - Polymer Degradation and Stability
T1 - The thermal degradation of poly(di-n-hexyl itaconate) prepared in the presence of n-dodecyl mercaptan
EP - 349
IS - 3
SP - 345
VL - 42
DO - 10.1016/0141-3910(93)90230-G
ER -
@article{
author = "Popović, Ivanka and Katsikas, Lynne and Voloschuk, K.A. and Schrötter, S. and Veličković, Jovan S.",
year = "1993",
abstract = "The preparation of poly(di-n-hexyl itaconate) (PDHI) in the presence of the chain transfer agent n-dodecyl mercaptan resulted in polymers of increased thermal stability, owing to the suppression of the number of chain terminal double bonds. The polymers were characterised by Fourier transform IR (FTIR) spectroscopy and gel permeation chromatography. The differential thermogravimetry (DTG) curves of all the PDHI samples had two peaks, showing that degradation occurred in two stages. The area of the lower-temperature DTG peak correlated with the number of terminal double bonds.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Polymer Degradation and Stability",
title = "The thermal degradation of poly(di-n-hexyl itaconate) prepared in the presence of n-dodecyl mercaptan",
pages = "349-345",
number = "3",
volume = "42",
doi = "10.1016/0141-3910(93)90230-G"
}
Popović, I., Katsikas, L., Voloschuk, K.A., Schrötter, S.,& Veličković, J. S.. (1993). The thermal degradation of poly(di-n-hexyl itaconate) prepared in the presence of n-dodecyl mercaptan. in Polymer Degradation and Stability
Elsevier Sci Ltd, Oxford., 42(3), 345-349.
https://doi.org/10.1016/0141-3910(93)90230-G
Popović I, Katsikas L, Voloschuk K, Schrötter S, Veličković JS. The thermal degradation of poly(di-n-hexyl itaconate) prepared in the presence of n-dodecyl mercaptan. in Polymer Degradation and Stability. 1993;42(3):345-349.
doi:10.1016/0141-3910(93)90230-G .
Popović, Ivanka, Katsikas, Lynne, Voloschuk, K.A., Schrötter, S., Veličković, Jovan S., "The thermal degradation of poly(di-n-hexyl itaconate) prepared in the presence of n-dodecyl mercaptan" in Polymer Degradation and Stability, 42, no. 3 (1993):345-349,
https://doi.org/10.1016/0141-3910(93)90230-G . .
