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Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K
An experimental analysis of density, refractive index, speed of sound and the viscosity at atmospheric pressure and temperatures T = (288.15 to 323.15) K has been carried out for the three binary systems, i.e. (p-cymene + alpha-pinene), (p-cymene + limonene) and (p-cymene + citral). Excess molar volumes, viscosity deviations, deviations in isentropic compressibility and excess Gibbs free energy of activation of viscous flow were calculated from experimental data. The results were fitted employing Redlich-Kister polynomial equation. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated to elucidate the non-ideal behavior of investigated mixtures. Furthermore, Prigogine-Flory-Patterson (PFP) model was successfully applied for the correlation of excess molar volumes of examined binary mixtures. The results of excess molar volume correlations show very good agreement with experimental measurement.
TY - JOUR
AU - Ilic-Pajic, Jovana
AU - Radović, Ivona
AU - Grozdanić, Nikola
AU - Stajic-Trosic, Jasna
AU - Kijevčanin, Mirjana
PY - 2021
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4809
AB - An experimental analysis of density, refractive index, speed of sound and the viscosity at atmospheric pressure and temperatures T = (288.15 to 323.15) K has been carried out for the three binary systems, i.e. (p-cymene + alpha-pinene), (p-cymene + limonene) and (p-cymene + citral). Excess molar volumes, viscosity deviations, deviations in isentropic compressibility and excess Gibbs free energy of activation of viscous flow were calculated from experimental data. The results were fitted employing Redlich-Kister polynomial equation. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated to elucidate the non-ideal behavior of investigated mixtures. Furthermore, Prigogine-Flory-Patterson (PFP) model was successfully applied for the correlation of excess molar volumes of examined binary mixtures. The results of excess molar volume correlations show very good agreement with experimental measurement.
T2 - Journal of Molecular Liquids
T1 - Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K
VL - 344
DO - 10.1016/j.molliq.2021.117486
ER -
@article{
author = "Ilic-Pajic, Jovana and Radović, Ivona and Grozdanić, Nikola and Stajic-Trosic, Jasna and Kijevčanin, Mirjana",
year = "2021",
abstract = "An experimental analysis of density, refractive index, speed of sound and the viscosity at atmospheric pressure and temperatures T = (288.15 to 323.15) K has been carried out for the three binary systems, i.e. (p-cymene + alpha-pinene), (p-cymene + limonene) and (p-cymene + citral). Excess molar volumes, viscosity deviations, deviations in isentropic compressibility and excess Gibbs free energy of activation of viscous flow were calculated from experimental data. The results were fitted employing Redlich-Kister polynomial equation. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated to elucidate the non-ideal behavior of investigated mixtures. Furthermore, Prigogine-Flory-Patterson (PFP) model was successfully applied for the correlation of excess molar volumes of examined binary mixtures. The results of excess molar volume correlations show very good agreement with experimental measurement.",
journal = "Journal of Molecular Liquids",
title = "Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K",
volume = "344",
doi = "10.1016/j.molliq.2021.117486"
}
Ilic-Pajic, J., Radović, I., Grozdanić, N., Stajic-Trosic, J.,& Kijevčanin, M.. (2021). Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K. in Journal of Molecular Liquids, 344.
https://doi.org/10.1016/j.molliq.2021.117486
Ilic-Pajic J, Radović I, Grozdanić N, Stajic-Trosic J, Kijevčanin M. Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K. in Journal of Molecular Liquids. 2021;344.
doi:10.1016/j.molliq.2021.117486 .
Ilic-Pajic, Jovana, Radović, Ivona, Grozdanić, Nikola, Stajic-Trosic, Jasna, Kijevčanin, Mirjana, "Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K" in Journal of Molecular Liquids, 344 (2021),
https://doi.org/10.1016/j.molliq.2021.117486 . .
