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dc.creatorIlic-Pajic, Jovana
dc.creatorRadović, Ivona
dc.creatorGrozdanić, Nikola
dc.creatorStajic-Trosic, Jasna
dc.creatorKijevčanin, Mirjana
dc.date.accessioned2022-03-04T11:17:28Z
dc.date.available2022-03-04T11:17:28Z
dc.date.issued2021
dc.identifier.issn0167-7322
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/4809
dc.description.abstractAn experimental analysis of density, refractive index, speed of sound and the viscosity at atmospheric pressure and temperatures T = (288.15 to 323.15) K has been carried out for the three binary systems, i.e. (p-cymene + alpha-pinene), (p-cymene + limonene) and (p-cymene + citral). Excess molar volumes, viscosity deviations, deviations in isentropic compressibility and excess Gibbs free energy of activation of viscous flow were calculated from experimental data. The results were fitted employing Redlich-Kister polynomial equation. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated to elucidate the non-ideal behavior of investigated mixtures. Furthermore, Prigogine-Flory-Patterson (PFP) model was successfully applied for the correlation of excess molar volumes of examined binary mixtures. The results of excess molar volume correlations show very good agreement with experimental measurement.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200135/RS//
dc.rightsrestrictedAccess
dc.sourceJournal of Molecular Liquids
dc.subjectP-cymeneen
dc.subjectTerpenesen
dc.subjectBinary mixturesen
dc.subjectThermophysical propertiesen
dc.subjectPrigogine-Flory-Patterson modelen
dc.titleVolumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 Ken
dc.typearticle
dc.rights.licenseARR
dc.citation.other344(): -
dc.citation.rankM21
dc.citation.volume344
dc.identifier.doi10.1016/j.molliq.2021.117486
dc.identifier.scopus2-s2.0-85116876147
dc.identifier.wos000708714300001
dc.type.versionpublishedVersion


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