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dc.creatorKojic, Marija M.
dc.creatorPetrovic, Jelena T.
dc.creatorPetrovic, Marija S.
dc.creatorStankovic, Slavka M.
dc.creatorPorobic, Slavica J.
dc.creatorMarinovic-Cincovic, Milena T.
dc.creatorMihajlovic, Marija L.
dc.date.accessioned2022-03-04T11:22:00Z
dc.date.available2022-03-04T11:22:00Z
dc.date.issued2021
dc.identifier.issn0165-2370
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/4884
dc.description.abstractHydrothermal carbonization (HTC) was employed for the conversion of the spent mushroom substrate (SMS) into a carbonaceous hydrochar. The effect of operating temperature (180, 200, 220, 240, and 260 ?C) on the physicochemical, structural, and combustion properties of the obtained hydrochars was analyzed. The HTC treatment caused the increase of the higher heating value (HHV) and the lower heating value (LHV) of hydrochars for 58 % and 65 % in comparison with SMS, respectively. Analysis of morphology and functional groups showed the formation of microspheres and cracks on the hydrochar surface, which are predominantly dominated by aromatic and oxygen-rich functional groups. Thermal and kinetics analysis showed that HTC treatment improves the combustion behavior of the obtained solids. Combustion kinetic parameters of SMS and hydrochars were determined by the methods of Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO). The thermodynamic parameters and pre-exponential factors reveal a complex mechanism of SMS and hydrochars decomposition process.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/31003/RS//
dc.rightsrestrictedAccess
dc.sourceJournal of Analytical and Applied Pyrolysis
dc.subjectSpent mushroom substrateen
dc.subjectHydrothermal carbonizationen
dc.subjectHydrocharen
dc.subjectIsoconversionalen
dc.subjectCombustion kineticen
dc.subjectThermodynamic analysisen
dc.titleHydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic studyen
dc.typearticle
dc.rights.licenseARR
dc.citation.other155(): -
dc.citation.rankM21
dc.citation.volume155
dc.identifier.doi10.1016/j.jaap.2021.105028
dc.identifier.scopus2-s2.0-85103726273
dc.identifier.wos000640938600001
dc.type.versionpublishedVersion


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