2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
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2021
Authors
Ristic, PredragFilipovic, Nenad
Blagojevic, Vladimir
Cirković, Jovana
Hollo, Berta Barta
Đokić, Veljko

Donnard, Morgan
Gulea, Mihaela
Marjanovic, Ivana
Klisuric, Olivera R.
Todorovic, Tamara R.
Article (Published version)

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Four silver-based coordination polymers, {[Ag(L1)(2)]NO3}(infinity) (1), {[Ag(L1)(2)]ClO4}(infinity) (2), {[Ag(L2)(2)]NO3 center dot H2O}(infinity) (3) and {[Ag(L2)(2)]ClO4}(infinity) (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min(-1). The best result was obtained for compound ...4, which can be correlated to its largest lattice volume.
Source:
Crystengcomm, 2021, 23, 27, 4799-4815Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200175 (Institute of Technical Sciences of SASA, Belgrade) (RS-200175)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200116 (University of Belgrade, Faculty of Agriculture) (RS-200116)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-200135)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200168 (University of Belgrade, Faculty of Chemistry) (RS-200168)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200125 (University of Novi Sad, Faculty of Science) (RS-200125)
DOI: 10.1039/d1ce00394a
ISSN: 1466-8033
WoS: 000664682100001
Scopus: 2-s2.0-85110010702
Institution/Community
Inovacioni centarTY - JOUR AU - Ristic, Predrag AU - Filipovic, Nenad AU - Blagojevic, Vladimir AU - Cirković, Jovana AU - Hollo, Berta Barta AU - Đokić, Veljko AU - Donnard, Morgan AU - Gulea, Mihaela AU - Marjanovic, Ivana AU - Klisuric, Olivera R. AU - Todorovic, Tamara R. PY - 2021 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4924 AB - Four silver-based coordination polymers, {[Ag(L1)(2)]NO3}(infinity) (1), {[Ag(L1)(2)]ClO4}(infinity) (2), {[Ag(L2)(2)]NO3 center dot H2O}(infinity) (3) and {[Ag(L2)(2)]ClO4}(infinity) (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min(-1). The best result was obtained for compound 4, which can be correlated to its largest lattice volume. T2 - Crystengcomm T1 - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior EP - 4815 IS - 27 SP - 4799 VL - 23 DO - 10.1039/d1ce00394a ER -
@article{ author = "Ristic, Predrag and Filipovic, Nenad and Blagojevic, Vladimir and Cirković, Jovana and Hollo, Berta Barta and Đokić, Veljko and Donnard, Morgan and Gulea, Mihaela and Marjanovic, Ivana and Klisuric, Olivera R. and Todorovic, Tamara R.", year = "2021", abstract = "Four silver-based coordination polymers, {[Ag(L1)(2)]NO3}(infinity) (1), {[Ag(L1)(2)]ClO4}(infinity) (2), {[Ag(L2)(2)]NO3 center dot H2O}(infinity) (3) and {[Ag(L2)(2)]ClO4}(infinity) (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min(-1). The best result was obtained for compound 4, which can be correlated to its largest lattice volume.", journal = "Crystengcomm", title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior", pages = "4815-4799", number = "27", volume = "23", doi = "10.1039/d1ce00394a" }
Ristic, P., Filipovic, N., Blagojevic, V., Cirković, J., Hollo, B. B., Đokić, V., Donnard, M., Gulea, M., Marjanovic, I., Klisuric, O. R.,& Todorovic, T. R.. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in Crystengcomm, 23(27), 4799-4815. https://doi.org/10.1039/d1ce00394a
Ristic P, Filipovic N, Blagojevic V, Cirković J, Hollo BB, Đokić V, Donnard M, Gulea M, Marjanovic I, Klisuric OR, Todorovic TR. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in Crystengcomm. 2021;23(27):4799-4815. doi:10.1039/d1ce00394a .
Ristic, Predrag, Filipovic, Nenad, Blagojevic, Vladimir, Cirković, Jovana, Hollo, Berta Barta, Đokić, Veljko, Donnard, Morgan, Gulea, Mihaela, Marjanovic, Ivana, Klisuric, Olivera R., Todorovic, Tamara R., "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" in Crystengcomm, 23, no. 27 (2021):4799-4815, https://doi.org/10.1039/d1ce00394a . .