Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study
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2022
Authors
Pijovic, MilenaManic, Nebojsa
Vasic-Anicijevic, Dragana
Krstic, Aleksandar
Mitric, Miodrag
Matić, Tamara
Jankovic, Bojan
Article (Published version)
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Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 degrees C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2.g- 1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from pi-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nit...rogen and electron-rich surface groups.
Keywords:
Waste tires / Recycling / Pyrolysis / Graphene-based adsorbent / Surface properties / DFTSource:
Diamond and Related Materials, 2022, 121Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (RS-MESTD-inst-2020-200017)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200105 (University of Belgrade, Faculty of Mechanical Engineering) (RS-MESTD-inst-2020-200105)
DOI: 10.1016/j.diamond.2021.108768
ISSN: 0925-9635
WoS: 000733634900004
Scopus: 2-s2.0-85121014167
Institution/Community
Inovacioni centarTY - JOUR AU - Pijovic, Milena AU - Manic, Nebojsa AU - Vasic-Anicijevic, Dragana AU - Krstic, Aleksandar AU - Mitric, Miodrag AU - Matić, Tamara AU - Jankovic, Bojan PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5015 AB - Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 degrees C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2.g- 1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from pi-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups. T2 - Diamond and Related Materials T1 - Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study VL - 121 DO - 10.1016/j.diamond.2021.108768 ER -
@article{ author = "Pijovic, Milena and Manic, Nebojsa and Vasic-Anicijevic, Dragana and Krstic, Aleksandar and Mitric, Miodrag and Matić, Tamara and Jankovic, Bojan", year = "2022", abstract = "Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 degrees C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2.g- 1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from pi-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups.", journal = "Diamond and Related Materials", title = "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study", volume = "121", doi = "10.1016/j.diamond.2021.108768" }
Pijovic, M., Manic, N., Vasic-Anicijevic, D., Krstic, A., Mitric, M., Matić, T.,& Jankovic, B.. (2022). Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials, 121. https://doi.org/10.1016/j.diamond.2021.108768
Pijovic M, Manic N, Vasic-Anicijevic D, Krstic A, Mitric M, Matić T, Jankovic B. Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials. 2022;121. doi:10.1016/j.diamond.2021.108768 .
Pijovic, Milena, Manic, Nebojsa, Vasic-Anicijevic, Dragana, Krstic, Aleksandar, Mitric, Miodrag, Matić, Tamara, Jankovic, Bojan, "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study" in Diamond and Related Materials, 121 (2022), https://doi.org/10.1016/j.diamond.2021.108768 . .