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Formation of AlPO4-15 and CoAPO-15 in the presence of hexamethylenetetramine

Authorized Users Only
1990
Authors
Rajić, Nevenka
Stojaković, Djordje
Kaučič, Venčeslav
Article (Published version)
Metadata
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Abstract
Two materials, AIPO4-15 and CoAPO-15, with the same aluminophosphate lattice have been obtained by hydrothermal synthesis in the presence of hexamethylenetetramine (HMTA). Their formation is attributed to the influence of species that arise through the decomposition of HMTA, the latter process taking place under synthetic conditions. The Co 2+ ion in CoAPO-15 occupies tetragonally deformed octahedral sites, and this causes a slight expansion of the unit cell of CoAPO-15 in comparison to that of AIPO4-15. The Co 2+ ion is coordinated not only by the O atoms of the system but also by NH3 molecules.
Keywords:
AlPO4-15 / CoAlPO-15 / Co(II) coordination / molecular sieve synthesis / organic template
Source:
Zeolites, 1990, 10, 8, 802-805
Publisher:
  • Butterworth-Heinemann
Funding / projects:
  • Research Community of Slovenia
  • Research Fund of SR Serbia, Yugoslavia

DOI: https://doi.org/10.1016/0144-2449(90)90066-Z

ISSN: 0144-2449

[ Google Scholar ]
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5060
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Rajić, Nevenka
AU  - Stojaković, Djordje
AU  - Kaučič, Venčeslav
PY  - 1990
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5060
AB  - Two materials, AIPO4-15 and CoAPO-15, with the same aluminophosphate lattice have been obtained by hydrothermal synthesis in the presence of hexamethylenetetramine (HMTA). Their formation is attributed to the influence of species that arise through the decomposition of HMTA, the latter process taking place under synthetic conditions. The Co 2+ ion in CoAPO-15 occupies tetragonally deformed octahedral sites, and this causes a slight expansion of the unit cell of CoAPO-15 in comparison to that of AIPO4-15. The Co 2+ ion is coordinated not only by the O atoms of the system but also by NH3 molecules.
PB  - Butterworth-Heinemann
T2  - Zeolites
T1  - Formation of AlPO4-15 and CoAPO-15 in the presence of hexamethylenetetramine
EP  - 805
IS  - 8
SP  - 802
VL  - 10
DO  - https://doi.org/10.1016/0144-2449(90)90066-Z
ER  - 
@article{
author = "Rajić, Nevenka and Stojaković, Djordje and Kaučič, Venčeslav",
year = "1990",
abstract = "Two materials, AIPO4-15 and CoAPO-15, with the same aluminophosphate lattice have been obtained by hydrothermal synthesis in the presence of hexamethylenetetramine (HMTA). Their formation is attributed to the influence of species that arise through the decomposition of HMTA, the latter process taking place under synthetic conditions. The Co 2+ ion in CoAPO-15 occupies tetragonally deformed octahedral sites, and this causes a slight expansion of the unit cell of CoAPO-15 in comparison to that of AIPO4-15. The Co 2+ ion is coordinated not only by the O atoms of the system but also by NH3 molecules.",
publisher = "Butterworth-Heinemann",
journal = "Zeolites",
title = "Formation of AlPO4-15 and CoAPO-15 in the presence of hexamethylenetetramine",
pages = "805-802",
number = "8",
volume = "10",
doi = "https://doi.org/10.1016/0144-2449(90)90066-Z"
}
Rajić, N., Stojaković, D.,& Kaučič, V.. (1990). Formation of AlPO4-15 and CoAPO-15 in the presence of hexamethylenetetramine. in Zeolites
Butterworth-Heinemann., 10(8), 802-805.
https://doi.org/https://doi.org/10.1016/0144-2449(90)90066-Z
Rajić N, Stojaković D, Kaučič V. Formation of AlPO4-15 and CoAPO-15 in the presence of hexamethylenetetramine. in Zeolites. 1990;10(8):802-805.
doi:https://doi.org/10.1016/0144-2449(90)90066-Z .
Rajić, Nevenka, Stojaković, Djordje, Kaučič, Venčeslav, "Formation of AlPO4-15 and CoAPO-15 in the presence of hexamethylenetetramine" in Zeolites, 10, no. 8 (1990):802-805,
https://doi.org/https://doi.org/10.1016/0144-2449(90)90066-Z . .

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