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Synthesis and characterization of the CoSAPO- 14 and CoSAPO-34

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1990
Authors
Rajić, Nevenka
Kaučič, Venčeslav
Stojaković, Djordje
article (publishedVersion)
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Abstract
The hydrothermal synthesis of CoSAPO-14 and CoSAPO-34 in the presence of isopropylamine as the template is described. CoSAPO-14 is a new MeSAPO material that predominantly forms at 125°C, whereas CoSAPO-34 is the main product at 160°C. CoSAPO-14 has a triclinic and CoSAPO-34 has a trigonal unit cell. Both materials contain in their cavities a template that is hydrogen-bonded to the lattice. The synthesis in the presence of Co 2+ ions is much more sensitive to the composition of the reaction gel than is usually found in the preparation of SAPO materials.
Keywords:
Molecular sieve synthesis / gel chemistry / CoSAPO molecular sieves / organic template / cobalt(ll) coordination
Source:
Zeolites, 1990, 10, 8, -169
Publisher:
  • Butterworth Publishers
Funding / projects:
  • Research Community of Slovenia
  • Research Fund of SR Serbia, Yugoslavia

DOI: 10.1016/0144-2449(90)90041-O

ISSN: 0144-2449

Scopus: 2-s2.0-0025401006
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URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5061
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  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet

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