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A novel triclinically deformed chabazite-like aluminophosphate prepared in the presence of tris(1,2-diaminoethane)nickel(II) chloride
dc.creator | Rajić, Nevenka | |
dc.creator | Meden, Anton | |
dc.creator | Sarv, Priit | |
dc.creator | Kaučič, Venčeslav | |
dc.date.accessioned | 2022-04-18T13:13:42Z | |
dc.date.available | 2022-04-18T13:13:42Z | |
dc.date.issued | 1998 | |
dc.identifier.issn | 1387-1811 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5063 | |
dc.description.abstract | The tris(1,2-diaminoethane)nickel(II) complex was found to be a novel structure-directing agent for the preparation of the chabazite-like AlPO4-34 molecular sieve. During crystallization the complex undergoes a ligand exchange, thus helping stabilization of the AlPO4's chabazite structure by hydroxyls that have exchanged one 1,2-diaminoethane (en) molecule from the Ni(II) coordination sphere. The exchanged complex, [Ni(en)2(OH)2], remains in the chabazite host causing a triclinic deformation of the rhombohedral chabazite framework. Upon calcination the triclinic phase completely transforms into the rhombohedral chabazite-like AlPO4-34 as evidenced from the in situ XRD pattern. | sr |
dc.language.iso | en | sr |
dc.publisher | Elsevier | sr |
dc.relation | Estonian Science Foundation (grant No 2302) | sr |
dc.rights | restrictedAccess | sr |
dc.source | Microporous and Mesoporous Materials | sr |
dc.subject | Molecular sieve | sr |
dc.subject | Triclinic precursor | sr |
dc.subject | Chabazite aluminophosphate | sr |
dc.subject | AlPO4-34 | sr |
dc.subject | Ni(II) complex | sr |
dc.title | A novel triclinically deformed chabazite-like aluminophosphate prepared in the presence of tris(1,2-diaminoethane)nickel(II) chloride | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dc.citation.epage | 87 | |
dc.citation.issue | 1-3 | |
dc.citation.spage | 83 | |
dc.citation.volume | 24 | |
dc.identifier.doi | 10.1016/S1387-1811(98)00146-2 | |
dc.identifier.scopus | 2-s2.0-0032180455 | |
dc.identifier.wos | 000076763400009 | |
dc.type.version | publishedVersion | sr |