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Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis

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2018
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Authors
Vasić, Milica V.
Pezo, Lato L.
Zdravković, Jelena D.
Vrebalov, Marija
Radojević, Zagorka
Article (Published version)
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Abstract
This research describes a study of 11 selected samples of brick clays applied in roofing tile production, by using simultaneous thermal analysis. Additionally, the laboratory-sized samples were prepared and fired (850-950 °C) and technological properties were determined. Mathematical analysis was applied to sum all the experimental results and help discriminate the samples by their behavior during firing. The samples, very similar according to mineralogical and chemical content, as well as granulometry tests, were successfully grouped using principal component analysis (PCA). The PCA was used to explore and easily visualize the differences between samples. The PCA performed for differential thermal analysis (DTA), differential scanning calorimetry (DSC) and differential thermogravimetry (DTG) curves clearly showed that the heat flow was mainly influenced by carbonate content and its grain size, while DTG discriminated samples according to the contents of clay minerals and carbonates. I...n addition, dilatometry analysis revealed which samples underwent the highest densification during the firing process. The PCA analysis of fired products properties showed that the highest correlations were between water absorption with firing shrinkage and compressive strength.

Keywords:
Brick clay / Thermal analyses / Principal component analysis / Dilatometry
Source:
Science of Sintering, 2018, 50, 4, 487-500
Publisher:
  • International Institute for the Science of Sintering
Funding / projects:
  • Development and application of multifunctional materials using domestic raw materials in upgraded processing lines (RS-45008)
  • Osmotic dehydration of food - energy and ecological aspects of sustainable production (RS-31055)
  • Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (RS-45007)

DOI: 10.2298/SOS1804487V

ISSN: 0350-820X

WoS: 000455876800010

Scopus: 2-s2.0-85070027120
[ Google Scholar ]
12
6
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5091
Collections
  • Radovi istraživača (Inovacioni centar) / Researchers’ publications (Innovation Centre)
Institution/Community
Inovacioni centar
TY  - JOUR
AU  - Vasić, Milica V.
AU  - Pezo, Lato L.
AU  - Zdravković, Jelena D.
AU  - Vrebalov, Marija
AU  - Radojević, Zagorka
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5091
AB  - This research describes a study of 11 selected samples of brick clays applied in roofing tile production, by using simultaneous thermal analysis. Additionally, the laboratory-sized samples were prepared and fired (850-950 °C) and technological properties were determined. Mathematical analysis was applied to sum all the experimental results and help discriminate the samples by their behavior during firing. The samples, very similar according to mineralogical and chemical content, as well as granulometry tests, were successfully grouped using principal component analysis (PCA). The PCA was used to explore and easily visualize the differences between samples. The PCA performed for differential thermal analysis (DTA), differential scanning calorimetry (DSC) and differential thermogravimetry (DTG) curves clearly showed that the heat flow was mainly influenced by carbonate content and its grain size, while DTG discriminated samples according to the contents of clay minerals and carbonates. In addition, dilatometry analysis revealed which samples underwent the highest densification during the firing process. The PCA analysis of fired products properties showed that the highest correlations were between water absorption with firing shrinkage and compressive strength.
PB  - International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis
EP  - 500
IS  - 4
SP  - 487
VL  - 50
DO  - 10.2298/SOS1804487V
ER  - 
@article{
author = "Vasić, Milica V. and Pezo, Lato L. and Zdravković, Jelena D. and Vrebalov, Marija and Radojević, Zagorka",
year = "2018",
abstract = "This research describes a study of 11 selected samples of brick clays applied in roofing tile production, by using simultaneous thermal analysis. Additionally, the laboratory-sized samples were prepared and fired (850-950 °C) and technological properties were determined. Mathematical analysis was applied to sum all the experimental results and help discriminate the samples by their behavior during firing. The samples, very similar according to mineralogical and chemical content, as well as granulometry tests, were successfully grouped using principal component analysis (PCA). The PCA was used to explore and easily visualize the differences between samples. The PCA performed for differential thermal analysis (DTA), differential scanning calorimetry (DSC) and differential thermogravimetry (DTG) curves clearly showed that the heat flow was mainly influenced by carbonate content and its grain size, while DTG discriminated samples according to the contents of clay minerals and carbonates. In addition, dilatometry analysis revealed which samples underwent the highest densification during the firing process. The PCA analysis of fired products properties showed that the highest correlations were between water absorption with firing shrinkage and compressive strength.",
publisher = "International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis",
pages = "500-487",
number = "4",
volume = "50",
doi = "10.2298/SOS1804487V"
}
Vasić, M. V., Pezo, L. L., Zdravković, J. D., Vrebalov, M.,& Radojević, Z.. (2018). Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis. in Science of Sintering
International Institute for the Science of Sintering., 50(4), 487-500.
https://doi.org/10.2298/SOS1804487V
Vasić MV, Pezo LL, Zdravković JD, Vrebalov M, Radojević Z. Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis. in Science of Sintering. 2018;50(4):487-500.
doi:10.2298/SOS1804487V .
Vasić, Milica V., Pezo, Lato L., Zdravković, Jelena D., Vrebalov, Marija, Radojević, Zagorka, "Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis" in Science of Sintering, 50, no. 4 (2018):487-500,
https://doi.org/10.2298/SOS1804487V . .

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