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Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II)

Authorized Users Only
1989
Authors
Rajić, Nevenka
Stojaković, Djordje
Article (Published version)
Metadata
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Abstract
Synthesis of the peripherally substituted (phthalocyaninato)metal derivatives (NO2)4PcM (M α Ni, Co, Cu; NO2 groups are in 1,8,15,22- or 2,9,16,23-positions) is described, and their X-ray powder diffraction patterns, solubilities, electronic and infrared spectra, and thermal stability are reported. The complexes exhibit isomorphism and polymorphism, and they are more soluble than the corresponding MPcs. Their thermal stability increases in the series Co < Ni < Cu, being at the same time greater for the 2,9,16,23-tetranitro- than for the 1,8,15,22-tetranitro derivatives.
Keywords:
nitrophthalocyanines / copper(II) / nickel(II) / cobalt(II) / synthesis / properties
Source:
Journal of Coordination Chemistry, 1989, 19, 295-301
Publisher:
  • Taylor & Francis

DOI: 10.1080/00958978909408832

ISSN: 0095-8972

[ Google Scholar ]
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5099
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Rajić, Nevenka
AU  - Stojaković, Djordje
PY  - 1989
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5099
AB  - Synthesis of the peripherally substituted (phthalocyaninato)metal derivatives (NO2)4PcM (M α Ni, Co, Cu; NO2 groups are in 1,8,15,22- or 2,9,16,23-positions) is described, and their X-ray powder diffraction patterns, solubilities, electronic and infrared spectra, and thermal stability are reported. The complexes exhibit isomorphism and polymorphism, and they are more soluble than the corresponding MPcs. Their thermal stability increases in the series Co < Ni < Cu, being at the same time greater for the 2,9,16,23-tetranitro- than for the 1,8,15,22-tetranitro derivatives.
PB  - Taylor & Francis
T2  - Journal of Coordination Chemistry
T1  - Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II)
EP  - 301
SP  - 295
VL  - 19
DO  - 10.1080/00958978909408832
ER  - 
@article{
author = "Rajić, Nevenka and Stojaković, Djordje",
year = "1989",
abstract = "Synthesis of the peripherally substituted (phthalocyaninato)metal derivatives (NO2)4PcM (M α Ni, Co, Cu; NO2 groups are in 1,8,15,22- or 2,9,16,23-positions) is described, and their X-ray powder diffraction patterns, solubilities, electronic and infrared spectra, and thermal stability are reported. The complexes exhibit isomorphism and polymorphism, and they are more soluble than the corresponding MPcs. Their thermal stability increases in the series Co < Ni < Cu, being at the same time greater for the 2,9,16,23-tetranitro- than for the 1,8,15,22-tetranitro derivatives.",
publisher = "Taylor & Francis",
journal = "Journal of Coordination Chemistry",
title = "Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II)",
pages = "301-295",
volume = "19",
doi = "10.1080/00958978909408832"
}
Rajić, N.,& Stojaković, D.. (1989). Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II). in Journal of Coordination Chemistry
Taylor & Francis., 19, 295-301.
https://doi.org/10.1080/00958978909408832
Rajić N, Stojaković D. Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II). in Journal of Coordination Chemistry. 1989;19:295-301.
doi:10.1080/00958978909408832 .
Rajić, Nevenka, Stojaković, Djordje, "Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II)" in Journal of Coordination Chemistry, 19 (1989):295-301,
https://doi.org/10.1080/00958978909408832 . .

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