The osmotic coefficient of ZnCl2(aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4) mol . kg(-1) with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl2(aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer-Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl2 at T = 298.15 K. The formation of the ZnCl+ complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.
TY - JOUR
AU - Miladinović, Jelena
AU - Ninković, Rozalija
AU - Todorović, M.
AU - Jovanović, V
PY - 2003
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/510
AB - The osmotic coefficient of ZnCl2(aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4) mol . kg(-1) with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl2(aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer-Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl2 at T = 298.15 K. The formation of the ZnCl+ complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.
PB - Academic Press Ltd- Elsevier Science Ltd, London
T2 - Journal of Chemical Thermodynamics
T1 - Osmotic coefficient of the ZnCl2(aq) at T=298.15 K
EP - 1082
IS - 7
SP - 1073
VL - 35
DO - 10.1016/S0021-9614(03)00048-X
ER -
@article{
author = "Miladinović, Jelena and Ninković, Rozalija and Todorović, M. and Jovanović, V",
year = "2003",
abstract = "The osmotic coefficient of ZnCl2(aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4) mol . kg(-1) with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl2(aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer-Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl2 at T = 298.15 K. The formation of the ZnCl+ complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Osmotic coefficient of the ZnCl2(aq) at T=298.15 K",
pages = "1082-1073",
number = "7",
volume = "35",
doi = "10.1016/S0021-9614(03)00048-X"
}
Miladinović, J., Ninković, R., Todorović, M.,& Jovanović, V.. (2003). Osmotic coefficient of the ZnCl2(aq) at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 35(7), 1073-1082.
https://doi.org/10.1016/S0021-9614(03)00048-X
Miladinović J, Ninković R, Todorović M, Jovanović V. Osmotic coefficient of the ZnCl2(aq) at T=298.15 K. in Journal of Chemical Thermodynamics. 2003;35(7):1073-1082.
doi:10.1016/S0021-9614(03)00048-X .
Miladinović, Jelena, Ninković, Rozalija, Todorović, M., Jovanović, V, "Osmotic coefficient of the ZnCl2(aq) at T=298.15 K" in Journal of Chemical Thermodynamics, 35, no. 7 (2003):1073-1082,
https://doi.org/10.1016/S0021-9614(03)00048-X . .
