Colorless plate-like crystals (AIPO-1,2DAP) crystallize from a clear 'AlPO4-1,2-diaminopropane' reaction system. The results of elemental, thermal and FTIR analyses give the following chemical formula: (NH4+)(1,2-H(2)DAP)(2+)(AlP2O8)(3-), confirmed also by single crystal structure determination. The X-ray diffraction data collected at 150 K reveal the space group Pc2(1)n with a = 8.2788(2), b = 16.7882(3), c = 8.6608(2) Angstrom, and V = 1203.73(5) Angstrom(3). The AIPO-1,2DAP has a chain structure related to the aluminophosphate AlPO-enA structure. Two occluded cations, NH4+ and doubly protonated diamine, balance the negative charge and interact with the chain oxygen atoms via hydrogen bond network.
Keywords:
crystal structure / X-ray diffraction
Source:
Journal of Physics and Chemistry of Solids, 2003, 64, 7, 1097-1103
TY - JOUR
AU - Rajić, Nevenka
AU - Zabukovec-Logar, Nataša
AU - Golobić, Amalija
AU - Kaučič, Venčeslav
PY - 2003
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/517
AB - Colorless plate-like crystals (AIPO-1,2DAP) crystallize from a clear 'AlPO4-1,2-diaminopropane' reaction system. The results of elemental, thermal and FTIR analyses give the following chemical formula: (NH4+)(1,2-H(2)DAP)(2+)(AlP2O8)(3-), confirmed also by single crystal structure determination. The X-ray diffraction data collected at 150 K reveal the space group Pc2(1)n with a = 8.2788(2), b = 16.7882(3), c = 8.6608(2) Angstrom, and V = 1203.73(5) Angstrom(3). The AIPO-1,2DAP has a chain structure related to the aluminophosphate AlPO-enA structure. Two occluded cations, NH4+ and doubly protonated diamine, balance the negative charge and interact with the chain oxygen atoms via hydrogen bond network.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - Journal of Physics and Chemistry of Solids
T1 - Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent
EP - 1103
IS - 7
SP - 1097
VL - 64
DO - 10.1016/S0022-3697(03)00002-7
ER -
@article{
author = "Rajić, Nevenka and Zabukovec-Logar, Nataša and Golobić, Amalija and Kaučič, Venčeslav",
year = "2003",
abstract = "Colorless plate-like crystals (AIPO-1,2DAP) crystallize from a clear 'AlPO4-1,2-diaminopropane' reaction system. The results of elemental, thermal and FTIR analyses give the following chemical formula: (NH4+)(1,2-H(2)DAP)(2+)(AlP2O8)(3-), confirmed also by single crystal structure determination. The X-ray diffraction data collected at 150 K reveal the space group Pc2(1)n with a = 8.2788(2), b = 16.7882(3), c = 8.6608(2) Angstrom, and V = 1203.73(5) Angstrom(3). The AIPO-1,2DAP has a chain structure related to the aluminophosphate AlPO-enA structure. Two occluded cations, NH4+ and doubly protonated diamine, balance the negative charge and interact with the chain oxygen atoms via hydrogen bond network.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Journal of Physics and Chemistry of Solids",
title = "Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent",
pages = "1103-1097",
number = "7",
volume = "64",
doi = "10.1016/S0022-3697(03)00002-7"
}
Rajić, N., Zabukovec-Logar, N., Golobić, A.,& Kaučič, V.. (2003). Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent. in Journal of Physics and Chemistry of Solids
Pergamon-Elsevier Science Ltd, Oxford., 64(7), 1097-1103.
https://doi.org/10.1016/S0022-3697(03)00002-7
Rajić N, Zabukovec-Logar N, Golobić A, Kaučič V. Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent. in Journal of Physics and Chemistry of Solids. 2003;64(7):1097-1103.
doi:10.1016/S0022-3697(03)00002-7 .
Rajić, Nevenka, Zabukovec-Logar, Nataša, Golobić, Amalija, Kaučič, Venčeslav, "Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent" in Journal of Physics and Chemistry of Solids, 64, no. 7 (2003):1097-1103,
https://doi.org/10.1016/S0022-3697(03)00002-7 . .
