Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent
Само за регистроване кориснике
2003
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Colorless plate-like crystals (AIPO-1,2DAP) crystallize from a clear 'AlPO4-1,2-diaminopropane' reaction system. The results of elemental, thermal and FTIR analyses give the following chemical formula: (NH4+)(1,2-H(2)DAP)(2+)(AlP2O8)(3-), confirmed also by single crystal structure determination. The X-ray diffraction data collected at 150 K reveal the space group Pc2(1)n with a = 8.2788(2), b = 16.7882(3), c = 8.6608(2) Angstrom, and V = 1203.73(5) Angstrom(3). The AIPO-1,2DAP has a chain structure related to the aluminophosphate AlPO-enA structure. Two occluded cations, NH4+ and doubly protonated diamine, balance the negative charge and interact with the chain oxygen atoms via hydrogen bond network.
Кључне речи:
crystal structure / X-ray diffractionИзвор:
Journal of Physics and Chemistry of Solids, 2003, 64, 7, 1097-1103Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/S0022-3697(03)00002-7
ISSN: 0022-3697
WoS: 000182996800007
Scopus: 2-s2.0-0038216933
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Rajić, Nevenka AU - Zabukovec-Logar, Nataša AU - Golobić, Amalija AU - Kaučič, Venčeslav PY - 2003 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/517 AB - Colorless plate-like crystals (AIPO-1,2DAP) crystallize from a clear 'AlPO4-1,2-diaminopropane' reaction system. The results of elemental, thermal and FTIR analyses give the following chemical formula: (NH4+)(1,2-H(2)DAP)(2+)(AlP2O8)(3-), confirmed also by single crystal structure determination. The X-ray diffraction data collected at 150 K reveal the space group Pc2(1)n with a = 8.2788(2), b = 16.7882(3), c = 8.6608(2) Angstrom, and V = 1203.73(5) Angstrom(3). The AIPO-1,2DAP has a chain structure related to the aluminophosphate AlPO-enA structure. Two occluded cations, NH4+ and doubly protonated diamine, balance the negative charge and interact with the chain oxygen atoms via hydrogen bond network. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Journal of Physics and Chemistry of Solids T1 - Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent EP - 1103 IS - 7 SP - 1097 VL - 64 DO - 10.1016/S0022-3697(03)00002-7 ER -
@article{ author = "Rajić, Nevenka and Zabukovec-Logar, Nataša and Golobić, Amalija and Kaučič, Venčeslav", year = "2003", abstract = "Colorless plate-like crystals (AIPO-1,2DAP) crystallize from a clear 'AlPO4-1,2-diaminopropane' reaction system. The results of elemental, thermal and FTIR analyses give the following chemical formula: (NH4+)(1,2-H(2)DAP)(2+)(AlP2O8)(3-), confirmed also by single crystal structure determination. The X-ray diffraction data collected at 150 K reveal the space group Pc2(1)n with a = 8.2788(2), b = 16.7882(3), c = 8.6608(2) Angstrom, and V = 1203.73(5) Angstrom(3). The AIPO-1,2DAP has a chain structure related to the aluminophosphate AlPO-enA structure. Two occluded cations, NH4+ and doubly protonated diamine, balance the negative charge and interact with the chain oxygen atoms via hydrogen bond network.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Journal of Physics and Chemistry of Solids", title = "Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent", pages = "1103-1097", number = "7", volume = "64", doi = "10.1016/S0022-3697(03)00002-7" }
Rajić, N., Zabukovec-Logar, N., Golobić, A.,& Kaučič, V.. (2003). Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent. in Journal of Physics and Chemistry of Solids Pergamon-Elsevier Science Ltd, Oxford., 64(7), 1097-1103. https://doi.org/10.1016/S0022-3697(03)00002-7
Rajić N, Zabukovec-Logar N, Golobić A, Kaučič V. Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent. in Journal of Physics and Chemistry of Solids. 2003;64(7):1097-1103. doi:10.1016/S0022-3697(03)00002-7 .
Rajić, Nevenka, Zabukovec-Logar, Nataša, Golobić, Amalija, Kaučič, Venčeslav, "Synthesis and structure determination of a chain-like aluminophosphate obtained with 1,2-diaminopropane as the structure-directing agent" in Journal of Physics and Chemistry of Solids, 64, no. 7 (2003):1097-1103, https://doi.org/10.1016/S0022-3697(03)00002-7 . .