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Green manufacturing of high-value extracts from milk thistle seeds: Parameters that affect the supercritical CO2extraction process

Authorized Users Only
2022
Authors
Milovanović, Stoja
Lukić, Ivana
Kaminski, Piotr
Debczak, Agnieszka
Klimkowska, Kamila
Tyskiewicz, Katarzyna
Konkol, Marcin
Article (Published version)
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Abstract
The aim of this study was to provide insights into parameters that affect the oil extraction from an industrially valuable raw material (milk thistle) using green solvent supercritical CO2. The effect of plant origin, cultivation year, and seeds storage on extraction yield has been explored. Furthermore, the effects of high-pressure unit design and initial plant material amount have been examined. Pressure (200-450 bar) and temperature (40-80 °C) have been tested to improve the recovery of essential fatty acids and phenolic compounds. Moreover, solid residues after the material pretreatment and supercritical CO2 extraction served as the substrates for waste valorization. The characterization of obtained high-value extracts has been carried out by chromatographic (using gas chromatographs combined with mass spectrometer and flame ionization detection) and spectrophotometric assays (for total phenolic and flavonoid compounds as well as a radical scavenging ability). It was shown that the... tested supercritical CO2 extraction process parameters determined extraction kinetics and allowed the extract separation from raw milk thistle seeds and waste material (3-32 mass %) rich in linoleic acid (up to 515 mg/g) and total phenolic compounds (up to 30 mg GAE/g).

Keywords:
Fatty acid content / Silybum marianum / Supercritical carbon dioxide / Supercritical fluid extraction / Total phenolic compounds
Source:
Journal of CO2 Utilization, 2022, 63, 102134-
Publisher:
  • Elsevier Ltd
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-200135)

DOI: 10.1016/j.jcou.2022.102134

ISSN: 2212-9820

WoS: 00083166570000

Scopus: 2-s2.0-85134712884
[ Google Scholar ]
3
1
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5190
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Milovanović, Stoja
AU  - Lukić, Ivana
AU  - Kaminski, Piotr
AU  - Debczak, Agnieszka
AU  - Klimkowska, Kamila
AU  - Tyskiewicz, Katarzyna
AU  - Konkol, Marcin
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5190
AB  - The aim of this study was to provide insights into parameters that affect the oil extraction from an industrially valuable raw material (milk thistle) using green solvent supercritical CO2. The effect of plant origin, cultivation year, and seeds storage on extraction yield has been explored. Furthermore, the effects of high-pressure unit design and initial plant material amount have been examined. Pressure (200-450 bar) and temperature (40-80 °C) have been tested to improve the recovery of essential fatty acids and phenolic compounds. Moreover, solid residues after the material pretreatment and supercritical CO2 extraction served as the substrates for waste valorization. The characterization of obtained high-value extracts has been carried out by chromatographic (using gas chromatographs combined with mass spectrometer and flame ionization detection) and spectrophotometric assays (for total phenolic and flavonoid compounds as well as a radical scavenging ability). It was shown that the tested supercritical CO2 extraction process parameters determined extraction kinetics and allowed the extract separation from raw milk thistle seeds and waste material (3-32 mass %) rich in linoleic acid (up to 515 mg/g) and total phenolic compounds (up to 30 mg GAE/g).
PB  - Elsevier Ltd
T2  - Journal of CO2 Utilization
T1  - Green manufacturing of high-value extracts from milk thistle seeds: Parameters that affect the supercritical CO2extraction process
SP  - 102134
VL  - 63
DO  - 10.1016/j.jcou.2022.102134
ER  - 
@article{
author = "Milovanović, Stoja and Lukić, Ivana and Kaminski, Piotr and Debczak, Agnieszka and Klimkowska, Kamila and Tyskiewicz, Katarzyna and Konkol, Marcin",
year = "2022",
abstract = "The aim of this study was to provide insights into parameters that affect the oil extraction from an industrially valuable raw material (milk thistle) using green solvent supercritical CO2. The effect of plant origin, cultivation year, and seeds storage on extraction yield has been explored. Furthermore, the effects of high-pressure unit design and initial plant material amount have been examined. Pressure (200-450 bar) and temperature (40-80 °C) have been tested to improve the recovery of essential fatty acids and phenolic compounds. Moreover, solid residues after the material pretreatment and supercritical CO2 extraction served as the substrates for waste valorization. The characterization of obtained high-value extracts has been carried out by chromatographic (using gas chromatographs combined with mass spectrometer and flame ionization detection) and spectrophotometric assays (for total phenolic and flavonoid compounds as well as a radical scavenging ability). It was shown that the tested supercritical CO2 extraction process parameters determined extraction kinetics and allowed the extract separation from raw milk thistle seeds and waste material (3-32 mass %) rich in linoleic acid (up to 515 mg/g) and total phenolic compounds (up to 30 mg GAE/g).",
publisher = "Elsevier Ltd",
journal = "Journal of CO2 Utilization",
title = "Green manufacturing of high-value extracts from milk thistle seeds: Parameters that affect the supercritical CO2extraction process",
pages = "102134",
volume = "63",
doi = "10.1016/j.jcou.2022.102134"
}
Milovanović, S., Lukić, I., Kaminski, P., Debczak, A., Klimkowska, K., Tyskiewicz, K.,& Konkol, M.. (2022). Green manufacturing of high-value extracts from milk thistle seeds: Parameters that affect the supercritical CO2extraction process. in Journal of CO2 Utilization
Elsevier Ltd., 63, 102134.
https://doi.org/10.1016/j.jcou.2022.102134
Milovanović S, Lukić I, Kaminski P, Debczak A, Klimkowska K, Tyskiewicz K, Konkol M. Green manufacturing of high-value extracts from milk thistle seeds: Parameters that affect the supercritical CO2extraction process. in Journal of CO2 Utilization. 2022;63:102134.
doi:10.1016/j.jcou.2022.102134 .
Milovanović, Stoja, Lukić, Ivana, Kaminski, Piotr, Debczak, Agnieszka, Klimkowska, Kamila, Tyskiewicz, Katarzyna, Konkol, Marcin, "Green manufacturing of high-value extracts from milk thistle seeds: Parameters that affect the supercritical CO2extraction process" in Journal of CO2 Utilization, 63 (2022):102134,
https://doi.org/10.1016/j.jcou.2022.102134 . .

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