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dc.creatorMiladinović, Jelena
dc.creatorNinković, Rozalija
dc.creatorTodorović, Milica D.
dc.creatorJovanović, Vladislava M.
dc.date.accessioned2021-03-10T10:06:10Z
dc.date.available2021-03-10T10:06:10Z
dc.date.issued2003
dc.identifier.issn0095-9782
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/519
dc.description.abstractThe available literature data on the osmotic coefficient of ZnSO4(aq) at 25degreesC in the molality range from 0.1 to 4.3 mol-kg(-1) and new experimental data from 1.2 to 2.9 mol-kg(-1), at the same temperature, are presented. Selected values of the osmotic coefficient from all the data are analyzed using the Clegg-Pitzer-Brimblecombe model, the extended Pitzer model, and a semiempirical equation comprising a power series in molality added to the Debye-Huckel limiting law. The extended Pitzer equation and the Clegg-Pitzer-Brimblecombe equations give the best results in fitting the osmotic coefficient data. All three models are used to calculate ZnSO4 activity coefficients at 25degreesC in dilute solutions ( lt 0.1 mol-kg(-1)) for comparison with published values.en
dc.publisherKluwer Academic/Plenum Publ, New York
dc.rightsrestrictedAccess
dc.sourceJournal of Solution Chemistry
dc.subjectisopiestic measurementsen
dc.subjectzinc sulfateen
dc.subjectosmotic coefficienten
dc.subjectactivity coefficienten
dc.subjectextended Pitzer modelen
dc.subjectClegg-Pitzer-Brimblecombe modelen
dc.subjectsemiemprical equationen
dc.titleCorrelation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic modelsen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage383
dc.citation.issue4
dc.citation.other32(4): 371-383
dc.citation.rankM23
dc.citation.spage371
dc.citation.volume32
dc.identifier.doi10.1023/A:1023710022173
dc.identifier.rcubconv_2302
dc.identifier.scopus2-s2.0-0347003388
dc.identifier.wos000182849400006
dc.type.versionpublishedVersion


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