An improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers is presented. The method involves the deconvolution of differential thermogravimetric (TG) curves and the reconstruction of the corresponding TG curves of the individual thermal degradation processes, to which the Flynn-Wall method is then applied separately. The method is illustrated using poly(diisobutyl itaconate) as an example.
Source:
Journal of Physical Chemistry B, 2003, 107, 30, 7522-7525
TY - JOUR
AU - Katsikas, Lynne
AU - Popović, Ivanka
PY - 2003
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/521
AB - An improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers is presented. The method involves the deconvolution of differential thermogravimetric (TG) curves and the reconstruction of the corresponding TG curves of the individual thermal degradation processes, to which the Flynn-Wall method is then applied separately. The method is illustrated using poly(diisobutyl itaconate) as an example.
PB - Amer Chemical Soc, Washington
T2 - Journal of Physical Chemistry B
T1 - Improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers
EP - 7525
IS - 30
SP - 7522
VL - 107
DO - 10.1021/jp027865e
ER -
@article{
author = "Katsikas, Lynne and Popović, Ivanka",
year = "2003",
abstract = "An improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers is presented. The method involves the deconvolution of differential thermogravimetric (TG) curves and the reconstruction of the corresponding TG curves of the individual thermal degradation processes, to which the Flynn-Wall method is then applied separately. The method is illustrated using poly(diisobutyl itaconate) as an example.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry B",
title = "Improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers",
pages = "7525-7522",
number = "30",
volume = "107",
doi = "10.1021/jp027865e"
}
Katsikas, L.,& Popović, I.. (2003). Improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers. in Journal of Physical Chemistry B
Amer Chemical Soc, Washington., 107(30), 7522-7525.
https://doi.org/10.1021/jp027865e
Katsikas L, Popović I. Improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers. in Journal of Physical Chemistry B. 2003;107(30):7522-7525.
doi:10.1021/jp027865e .
Katsikas, Lynne, Popović, Ivanka, "Improvement to the Flynn-Wall method of determining apparent activation energies of the thermal degradation of polymers" in Journal of Physical Chemistry B, 107, no. 30 (2003):7522-7525,
https://doi.org/10.1021/jp027865e . .
