Sustainable Dyeing and Functionalization of Different Fibers Using Orange Peel Extract’s Antioxidants
Authors
Ivanovska, AleksandraGajić Savić, Ivana
Lađarević, Jelena
Milošević, Marija
Savić, Ivan
Mihajlovski, Katarina
Kostić, Mirjana
Article (Published version)
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A diluted ethanol orange peel extract was used for sustainable dyeing and functionalization of different fabrics. The extract analysis was performed using UPLC-ESI-MS/MS; its total flavonoid (0.67 g RE/100 g d.w.) and antioxidant (2.81 g GAE/100 g d.w.) contents and antioxidant activity (IC50 of 65.5 µg/mL) were also determined. The extract dyeing performance at various dyebath pH values was evaluated using multifiber fabric. Among six fabrics, extract possessed the ability for dyeing wool, polyamide, and cellulose acetate (at pH 4.5), which color strength (K/S) values increased after washing (9.7–19.8 vs. 11.6–23.2). Extract:water ratio of 20:35 (v/v) was found to be sufficient for achieving satisfactory K/S values (i.e., 20.17, 12.56, and 10.38 for wool, polyamide, and cellulose acetate, respectively) that were slightly changed after washing. The optimal dyeing temperatures for wool, polyamide, and cellulose acetate are 55, 35, and 25 °C, while the equilibrium dye exhaustion at those... temperatures was achieved after 45, 120, and 90 min, respectively. The color coordinate measurements revealed that wool and polyamide fabrics are yellower than cellulose acetate, while, compared to polyamide and cellulose acetate, wool is redder. Possible interactions between selected fabrics and extract compounds are suggested. All fabrics possessed excellent antioxidant activity (88.6–99.6%) both before and after washing. Cellulose acetate provided maximum bacterial reduction (99.99%) for Escherichia coli, and Staphylococcus aureus, which in the case of Staphylococcus aureus remained unchanged after washing. Orange peel extract could be used for simultaneous dyeing and functionalization of wool and polyamide (excellent antioxidant activity) and cellulose acetate (excellent antioxidant and antibacterial activity) fabrics.
Keywords:
antibacterial activity / antioxidant activity / cellulose acetate / functionalization / orange peel extract / polyamide / sustainable dyeing / woolSource:
Antioxidants, 2022, 11, 10, 2059-Publisher:
- MDPI
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200133 (Univeristy of Niš, Faculty of Technology, Leskovac) (RS-MESTD-inst-2020-200133)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-MESTD-inst-2020-200135)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200287 (Innovation Center of the Faculty of Technology and Metallurgy) (RS-MESTD-inst-2020-200287)
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Inovacioni centarTY - JOUR AU - Ivanovska, Aleksandra AU - Gajić Savić, Ivana AU - Lađarević, Jelena AU - Milošević, Marija AU - Savić, Ivan AU - Mihajlovski, Katarina AU - Kostić, Mirjana PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5237 AB - A diluted ethanol orange peel extract was used for sustainable dyeing and functionalization of different fabrics. The extract analysis was performed using UPLC-ESI-MS/MS; its total flavonoid (0.67 g RE/100 g d.w.) and antioxidant (2.81 g GAE/100 g d.w.) contents and antioxidant activity (IC50 of 65.5 µg/mL) were also determined. The extract dyeing performance at various dyebath pH values was evaluated using multifiber fabric. Among six fabrics, extract possessed the ability for dyeing wool, polyamide, and cellulose acetate (at pH 4.5), which color strength (K/S) values increased after washing (9.7–19.8 vs. 11.6–23.2). Extract:water ratio of 20:35 (v/v) was found to be sufficient for achieving satisfactory K/S values (i.e., 20.17, 12.56, and 10.38 for wool, polyamide, and cellulose acetate, respectively) that were slightly changed after washing. The optimal dyeing temperatures for wool, polyamide, and cellulose acetate are 55, 35, and 25 °C, while the equilibrium dye exhaustion at those temperatures was achieved after 45, 120, and 90 min, respectively. The color coordinate measurements revealed that wool and polyamide fabrics are yellower than cellulose acetate, while, compared to polyamide and cellulose acetate, wool is redder. Possible interactions between selected fabrics and extract compounds are suggested. All fabrics possessed excellent antioxidant activity (88.6–99.6%) both before and after washing. Cellulose acetate provided maximum bacterial reduction (99.99%) for Escherichia coli, and Staphylococcus aureus, which in the case of Staphylococcus aureus remained unchanged after washing. Orange peel extract could be used for simultaneous dyeing and functionalization of wool and polyamide (excellent antioxidant activity) and cellulose acetate (excellent antioxidant and antibacterial activity) fabrics. PB - MDPI T2 - Antioxidants T1 - Sustainable Dyeing and Functionalization of Different Fibers Using Orange Peel Extract’s Antioxidants IS - 10 SP - 2059 VL - 11 DO - 10.3390/antiox11102059 ER -
@article{ author = "Ivanovska, Aleksandra and Gajić Savić, Ivana and Lađarević, Jelena and Milošević, Marija and Savić, Ivan and Mihajlovski, Katarina and Kostić, Mirjana", year = "2022", abstract = "A diluted ethanol orange peel extract was used for sustainable dyeing and functionalization of different fabrics. The extract analysis was performed using UPLC-ESI-MS/MS; its total flavonoid (0.67 g RE/100 g d.w.) and antioxidant (2.81 g GAE/100 g d.w.) contents and antioxidant activity (IC50 of 65.5 µg/mL) were also determined. The extract dyeing performance at various dyebath pH values was evaluated using multifiber fabric. Among six fabrics, extract possessed the ability for dyeing wool, polyamide, and cellulose acetate (at pH 4.5), which color strength (K/S) values increased after washing (9.7–19.8 vs. 11.6–23.2). Extract:water ratio of 20:35 (v/v) was found to be sufficient for achieving satisfactory K/S values (i.e., 20.17, 12.56, and 10.38 for wool, polyamide, and cellulose acetate, respectively) that were slightly changed after washing. The optimal dyeing temperatures for wool, polyamide, and cellulose acetate are 55, 35, and 25 °C, while the equilibrium dye exhaustion at those temperatures was achieved after 45, 120, and 90 min, respectively. The color coordinate measurements revealed that wool and polyamide fabrics are yellower than cellulose acetate, while, compared to polyamide and cellulose acetate, wool is redder. Possible interactions between selected fabrics and extract compounds are suggested. All fabrics possessed excellent antioxidant activity (88.6–99.6%) both before and after washing. Cellulose acetate provided maximum bacterial reduction (99.99%) for Escherichia coli, and Staphylococcus aureus, which in the case of Staphylococcus aureus remained unchanged after washing. Orange peel extract could be used for simultaneous dyeing and functionalization of wool and polyamide (excellent antioxidant activity) and cellulose acetate (excellent antioxidant and antibacterial activity) fabrics.", publisher = "MDPI", journal = "Antioxidants", title = "Sustainable Dyeing and Functionalization of Different Fibers Using Orange Peel Extract’s Antioxidants", number = "10", pages = "2059", volume = "11", doi = "10.3390/antiox11102059" }
Ivanovska, A., Gajić Savić, I., Lađarević, J., Milošević, M., Savić, I., Mihajlovski, K.,& Kostić, M.. (2022). Sustainable Dyeing and Functionalization of Different Fibers Using Orange Peel Extract’s Antioxidants. in Antioxidants MDPI., 11(10), 2059. https://doi.org/10.3390/antiox11102059
Ivanovska A, Gajić Savić I, Lađarević J, Milošević M, Savić I, Mihajlovski K, Kostić M. Sustainable Dyeing and Functionalization of Different Fibers Using Orange Peel Extract’s Antioxidants. in Antioxidants. 2022;11(10):2059. doi:10.3390/antiox11102059 .
Ivanovska, Aleksandra, Gajić Savić, Ivana, Lađarević, Jelena, Milošević, Marija, Savić, Ivan, Mihajlovski, Katarina, Kostić, Mirjana, "Sustainable Dyeing and Functionalization of Different Fibers Using Orange Peel Extract’s Antioxidants" in Antioxidants, 11, no. 10 (2022):2059, https://doi.org/10.3390/antiox11102059 . .