Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells

Matović, Luka; Trišović, Nemanja; Lađarević, Jelena; Vitnik, Vesna; Vitnik, Željko; Yavuz, Cagdas; Sen, Burak; Yasir, Albashir; Sule Erten, Ela; Mijin, Dušan

doi:10.1016/j.molstruc.2022.134433

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2023

Authors

Matović, Luka

Trišović, Nemanja

Lađarević, Jelena

Vitnik, Vesna

Vitnik, Željko
Yavuz, Cagdas
Sen, Burak
Yasir, Albashir
Sule Erten, Ela
Mijin, Dušan

Article (Published version)

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Abstract

Five novel D-π-A structured pyridinium based compounds, bearing different electron-donating units were synthesized, minutely characterized, and their solvatochromic and electronic properties were investigated. Subsequently, these compounds were added to a liquid electrolyte in order to enhance the photovoltaic performance of the N719-sensitized solar cell. It was demonstrated that the utilization of all compounds improved the conversion efficiency, compared to the reference solar cell comprised of plain liquid electrolyte. The photovoltaic performance of the fabricated DSSC depended of the electron-donating moiety of the synthesized compound. The highest photovoltaic conversion efficiency of 4.11% was obtained for DSSC with the compound bearing the 4-(N,N-dimethylamino)phenyl group.

Keywords:

Charge transfer / DFT / DSSC / Pyridinium based compounds / UV–Vis spectroscopy

Source:
Journal of Molecular Structure, 2023, 1274, 134433-

Publisher:

Elsevier B.V.

Funding / projects:

DOI: 10.1016/j.molstruc.2022.134433

ISSN: 0022-2860

Scopus: 2-s2.0-85140887117

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URI

http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5241

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TY  - JOUR
AU  - Matović, Luka
AU  - Trišović, Nemanja
AU  - Lađarević, Jelena
AU  - Vitnik, Vesna
AU  - Vitnik, Željko
AU  - Yavuz, Cagdas
AU  - Sen, Burak
AU  - Yasir, Albashir
AU  - Sule Erten, Ela
AU  - Mijin, Dušan
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5241
AB  - Five novel D-π-A structured pyridinium based compounds, bearing different electron-donating units were synthesized, minutely characterized, and their solvatochromic and electronic properties were investigated. Subsequently, these compounds were added to a liquid electrolyte in order to enhance the photovoltaic performance of the N719-sensitized solar cell. It was demonstrated that the utilization of all compounds improved the conversion efficiency, compared to the reference solar cell comprised of plain liquid electrolyte. The photovoltaic performance of the fabricated DSSC depended of the electron-donating moiety of the synthesized compound. The highest photovoltaic conversion efficiency of 4.11% was obtained for DSSC with the compound bearing the 4-(N,N-dimethylamino)phenyl group.
PB  - Elsevier B.V.
T2  - Journal of Molecular Structure
T1  - Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells
SP  - 134433
VL  - 1274
DO  - 10.1016/j.molstruc.2022.134433
ER  -

@article{
author = "Matović, Luka and Trišović, Nemanja and Lađarević, Jelena and Vitnik, Vesna and Vitnik, Željko and Yavuz, Cagdas and Sen, Burak and Yasir, Albashir and Sule Erten, Ela and Mijin, Dušan",
year = "2023",
abstract = "Five novel D-π-A structured pyridinium based compounds, bearing different electron-donating units were synthesized, minutely characterized, and their solvatochromic and electronic properties were investigated. Subsequently, these compounds were added to a liquid electrolyte in order to enhance the photovoltaic performance of the N719-sensitized solar cell. It was demonstrated that the utilization of all compounds improved the conversion efficiency, compared to the reference solar cell comprised of plain liquid electrolyte. The photovoltaic performance of the fabricated DSSC depended of the electron-donating moiety of the synthesized compound. The highest photovoltaic conversion efficiency of 4.11% was obtained for DSSC with the compound bearing the 4-(N,N-dimethylamino)phenyl group.",
publisher = "Elsevier B.V.",
journal = "Journal of Molecular Structure",
title = "Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells",
pages = "134433",
volume = "1274",
doi = "10.1016/j.molstruc.2022.134433"
}

Matović, L., Trišović, N., Lađarević, J., Vitnik, V., Vitnik, Ž., Yavuz, C., Sen, B., Yasir, A., Sule Erten, E.,& Mijin, D.. (2023). Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells. in Journal of Molecular Structure
Elsevier B.V.., 1274, 134433.
https://doi.org/10.1016/j.molstruc.2022.134433

Matović L, Trišović N, Lađarević J, Vitnik V, Vitnik Ž, Yavuz C, Sen B, Yasir A, Sule Erten E, Mijin D. Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells. in Journal of Molecular Structure. 2023;1274:134433.
doi:10.1016/j.molstruc.2022.134433 .

Matović, Luka, Trišović, Nemanja, Lađarević, Jelena, Vitnik, Vesna, Vitnik, Željko, Yavuz, Cagdas, Sen, Burak, Yasir, Albashir, Sule Erten, Ela, Mijin, Dušan, "Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells" in Journal of Molecular Structure, 1274 (2023):134433,
https://doi.org/10.1016/j.molstruc.2022.134433 . .