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Nanomechanical properties of PVDF–ZnO polymer nanocomposite

Само за регистроване кориснике
2023
Аутори
Peleš Tadić, Adriana
Blagojević, Vladimir A.
Stojanović, Dušica
Ostojić, Sanja B.
Tasić, Nikola
Kosanović, Darko
Uskoković, Petar
Pavlović, Vladimir B.
Чланак у часопису (Објављена верзија)
Метаподаци
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Апстракт
Poly(vinylidenefluoride)–ZnO (PVDF–ZnO) nanocomposites with mechanically activated ZnO nanoparticle fillers were investigated using thermal and mechanical analysis and AFM and PFM. Differential scanning calorimetry (DSC) investigated the effect of ZnO nanoparticles on the crystallinity of the polymer, under controlled heating and cooling. Atomic force (AFM) microscopy was used to record the surfaces of the samples. Nanocomposite surface roughness shows the presence of the different phases inside of the matrix, where rough samples contain a higher proportion of the β phase. PFM was performed to investigate the piezoresponse of the composites. Nanoidentation showed that the mechanical activation of the filler (ZnO) increases the Young modulus with the activation time. Molecular simulations in periodic systems (PVDF–ZnO spherical nanocluster and nanocylinder composite) were used to investigate the influence of particle size and shape on the Young modulus of different phases of PVDF.
Кључне речи:
Mechanical activation / Nanoindentation / PFM / PVDF / ZnO
Извор:
Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 2023, 287, 116126-
Издавач:
  • Elsevier Ltd
Финансирање / пројекти:
  • Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-200135)
  • Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200051 (Институт за општу и физичку хемију, Београд) (RS-200051)
  • Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200053 (Универзитет у Београду, Институт за мултидисциплинарна истраживања) (RS-200053)
  • Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200175 (Институт техничких наука САНУ, Београд) (RS-200175)
  • Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-200116)

DOI: 10.1016/j.mseb.2022.116126

ISSN: 0921-5107

Scopus: 2-s2.0-85141443359
[ Google Scholar ]
2
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5264
Колекције
  • Radovi istraživača / Researchers’ publications (TMF)
Институција/група
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Peleš Tadić, Adriana
AU  - Blagojević, Vladimir A.
AU  - Stojanović, Dušica
AU  - Ostojić, Sanja B.
AU  - Tasić, Nikola
AU  - Kosanović, Darko
AU  - Uskoković, Petar
AU  - Pavlović, Vladimir B.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5264
AB  - Poly(vinylidenefluoride)–ZnO (PVDF–ZnO) nanocomposites with mechanically activated ZnO nanoparticle fillers were investigated using thermal and mechanical analysis and AFM and PFM. Differential scanning calorimetry (DSC) investigated the effect of ZnO nanoparticles on the crystallinity of the polymer, under controlled heating and cooling. Atomic force (AFM) microscopy was used to record the surfaces of the samples. Nanocomposite surface roughness shows the presence of the different phases inside of the matrix, where rough samples contain a higher proportion of the β phase. PFM was performed to investigate the piezoresponse of the composites. Nanoidentation showed that the mechanical activation of the filler (ZnO) increases the Young modulus with the activation time. Molecular simulations in periodic systems (PVDF–ZnO spherical nanocluster and nanocylinder composite) were used to investigate the influence of particle size and shape on the Young modulus of different phases of PVDF.
PB  - Elsevier Ltd
T2  - Materials Science and Engineering B: Solid-State Materials for Advanced Technology
T1  - Nanomechanical properties of PVDF–ZnO polymer nanocomposite
SP  - 116126
VL  - 287
DO  - 10.1016/j.mseb.2022.116126
ER  - 
@article{
author = "Peleš Tadić, Adriana and Blagojević, Vladimir A. and Stojanović, Dušica and Ostojić, Sanja B. and Tasić, Nikola and Kosanović, Darko and Uskoković, Petar and Pavlović, Vladimir B.",
year = "2023",
abstract = "Poly(vinylidenefluoride)–ZnO (PVDF–ZnO) nanocomposites with mechanically activated ZnO nanoparticle fillers were investigated using thermal and mechanical analysis and AFM and PFM. Differential scanning calorimetry (DSC) investigated the effect of ZnO nanoparticles on the crystallinity of the polymer, under controlled heating and cooling. Atomic force (AFM) microscopy was used to record the surfaces of the samples. Nanocomposite surface roughness shows the presence of the different phases inside of the matrix, where rough samples contain a higher proportion of the β phase. PFM was performed to investigate the piezoresponse of the composites. Nanoidentation showed that the mechanical activation of the filler (ZnO) increases the Young modulus with the activation time. Molecular simulations in periodic systems (PVDF–ZnO spherical nanocluster and nanocylinder composite) were used to investigate the influence of particle size and shape on the Young modulus of different phases of PVDF.",
publisher = "Elsevier Ltd",
journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",
title = "Nanomechanical properties of PVDF–ZnO polymer nanocomposite",
pages = "116126",
volume = "287",
doi = "10.1016/j.mseb.2022.116126"
}
Peleš Tadić, A., Blagojević, V. A., Stojanović, D., Ostojić, S. B., Tasić, N., Kosanović, D., Uskoković, P.,& Pavlović, V. B.. (2023). Nanomechanical properties of PVDF–ZnO polymer nanocomposite. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Elsevier Ltd., 287, 116126.
https://doi.org/10.1016/j.mseb.2022.116126
Peleš Tadić A, Blagojević VA, Stojanović D, Ostojić SB, Tasić N, Kosanović D, Uskoković P, Pavlović VB. Nanomechanical properties of PVDF–ZnO polymer nanocomposite. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2023;287:116126.
doi:10.1016/j.mseb.2022.116126 .
Peleš Tadić, Adriana, Blagojević, Vladimir A., Stojanović, Dušica, Ostojić, Sanja B., Tasić, Nikola, Kosanović, Darko, Uskoković, Petar, Pavlović, Vladimir B., "Nanomechanical properties of PVDF–ZnO polymer nanocomposite" in Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 287 (2023):116126,
https://doi.org/10.1016/j.mseb.2022.116126 . .

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