An Efficient Electrochemical Sensing of Caffeic Acid at Thermolysis Prepared Urea-formaldehyde Resin Modified with Fe(III) and Ti(IV) Oxide Particles
Аутори
Petković, Branka B.Kostić, Marija
Samaržija-Jovanović, Suzana
Ivanović, Aleksandra
Laban, Bojana
Veljović, Đorđe
Stanković, Dalibor M.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Urea-formaldehyde resin (UF) is primarily used as an adhesive applied in the wood composites industry. In this work, we found that this resin modified with metal compounds could be a good starting point to produce high-performance electrode material applied for the construction of electrochemical sensor for important antioxidant, such as caffeic acids (CA). The conductivity of carbon paste electrodes (CPE) modified by materials produced by thermolysis of in situ synthesized urea formaldehyde resins with Fe(III) and Ti(IV) compounds (mixed metal compounds and individually) were examined. For comparison, pure CPE and CPE modified with material produced from the physical mixture of UF resins and metal compounds in the same combinations were also electrochemically characterized by impedance spectroscopy and cyclic voltammetry. The most conductive material, which consists of a combination of metal oxide particles in situ synthesized with UF (SynFe+Ti/UF-TP@CPE), was used as a CPE modifier a...nd proved itself in sensitive differential pulse voltammetric determination of caffeic acid at a wide working range of 0.5-100 and limit of detection of 0.046 μM. The proposed electrode was successfully applied for the determination of the content of CA in spiked urine samples and the estimation of total phenol content, based on CA equivalents, of honey, liqueur and juice samples.
Кључне речи:
voltammetric sensor / caffeic acid / carbon paste electrode / urea-formaldehyde resin / metal oxide particles / antioxidant capacityИзвор:
International Journal of Electrochemical Science, 2022, 17, 221214-Издавач:
- Electrochemical Science Group
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200123 (Универзитет у Приштини са привременим седиштем у Косовској Митровици, Природно-математички факултет) (RS-200123)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200052 (Институт за рударство и металургију, Бор) (RS-200052)
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Petković, Branka B. AU - Kostić, Marija AU - Samaržija-Jovanović, Suzana AU - Ivanović, Aleksandra AU - Laban, Bojana AU - Veljović, Đorđe AU - Stanković, Dalibor M. PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5283 AB - Urea-formaldehyde resin (UF) is primarily used as an adhesive applied in the wood composites industry. In this work, we found that this resin modified with metal compounds could be a good starting point to produce high-performance electrode material applied for the construction of electrochemical sensor for important antioxidant, such as caffeic acids (CA). The conductivity of carbon paste electrodes (CPE) modified by materials produced by thermolysis of in situ synthesized urea formaldehyde resins with Fe(III) and Ti(IV) compounds (mixed metal compounds and individually) were examined. For comparison, pure CPE and CPE modified with material produced from the physical mixture of UF resins and metal compounds in the same combinations were also electrochemically characterized by impedance spectroscopy and cyclic voltammetry. The most conductive material, which consists of a combination of metal oxide particles in situ synthesized with UF (SynFe+Ti/UF-TP@CPE), was used as a CPE modifier and proved itself in sensitive differential pulse voltammetric determination of caffeic acid at a wide working range of 0.5-100 and limit of detection of 0.046 μM. The proposed electrode was successfully applied for the determination of the content of CA in spiked urine samples and the estimation of total phenol content, based on CA equivalents, of honey, liqueur and juice samples. PB - Electrochemical Science Group T2 - International Journal of Electrochemical Science T1 - An Efficient Electrochemical Sensing of Caffeic Acid at Thermolysis Prepared Urea-formaldehyde Resin Modified with Fe(III) and Ti(IV) Oxide Particles SP - 221214 VL - 17 DO - 10.20964/2022.12.04 ER -
@article{ author = "Petković, Branka B. and Kostić, Marija and Samaržija-Jovanović, Suzana and Ivanović, Aleksandra and Laban, Bojana and Veljović, Đorđe and Stanković, Dalibor M.", year = "2022", abstract = "Urea-formaldehyde resin (UF) is primarily used as an adhesive applied in the wood composites industry. In this work, we found that this resin modified with metal compounds could be a good starting point to produce high-performance electrode material applied for the construction of electrochemical sensor for important antioxidant, such as caffeic acids (CA). The conductivity of carbon paste electrodes (CPE) modified by materials produced by thermolysis of in situ synthesized urea formaldehyde resins with Fe(III) and Ti(IV) compounds (mixed metal compounds and individually) were examined. For comparison, pure CPE and CPE modified with material produced from the physical mixture of UF resins and metal compounds in the same combinations were also electrochemically characterized by impedance spectroscopy and cyclic voltammetry. The most conductive material, which consists of a combination of metal oxide particles in situ synthesized with UF (SynFe+Ti/UF-TP@CPE), was used as a CPE modifier and proved itself in sensitive differential pulse voltammetric determination of caffeic acid at a wide working range of 0.5-100 and limit of detection of 0.046 μM. The proposed electrode was successfully applied for the determination of the content of CA in spiked urine samples and the estimation of total phenol content, based on CA equivalents, of honey, liqueur and juice samples.", publisher = "Electrochemical Science Group", journal = "International Journal of Electrochemical Science", title = "An Efficient Electrochemical Sensing of Caffeic Acid at Thermolysis Prepared Urea-formaldehyde Resin Modified with Fe(III) and Ti(IV) Oxide Particles", pages = "221214", volume = "17", doi = "10.20964/2022.12.04" }
Petković, B. B., Kostić, M., Samaržija-Jovanović, S., Ivanović, A., Laban, B., Veljović, Đ.,& Stanković, D. M.. (2022). An Efficient Electrochemical Sensing of Caffeic Acid at Thermolysis Prepared Urea-formaldehyde Resin Modified with Fe(III) and Ti(IV) Oxide Particles. in International Journal of Electrochemical Science Electrochemical Science Group., 17, 221214. https://doi.org/10.20964/2022.12.04
Petković BB, Kostić M, Samaržija-Jovanović S, Ivanović A, Laban B, Veljović Đ, Stanković DM. An Efficient Electrochemical Sensing of Caffeic Acid at Thermolysis Prepared Urea-formaldehyde Resin Modified with Fe(III) and Ti(IV) Oxide Particles. in International Journal of Electrochemical Science. 2022;17:221214. doi:10.20964/2022.12.04 .
Petković, Branka B., Kostić, Marija, Samaržija-Jovanović, Suzana, Ivanović, Aleksandra, Laban, Bojana, Veljović, Đorđe, Stanković, Dalibor M., "An Efficient Electrochemical Sensing of Caffeic Acid at Thermolysis Prepared Urea-formaldehyde Resin Modified with Fe(III) and Ti(IV) Oxide Particles" in International Journal of Electrochemical Science, 17 (2022):221214, https://doi.org/10.20964/2022.12.04 . .