Electrochemical properties of RuO2-based electrode, particularly the oxygen evolution and anodic dissolution of RuO2 have been investigated in 0.5 mol dm-3 H2SO4 solution by means of polarization measurements and product analysis. It has been demonstrated that it is possible to determine very low concentration of dissolved ruthenium species (8 × 10-10 mol dm-3 Ru) by a sensitive spectrophotometric method based on the ruthenium-catalyzed ceric-arsenite reaction.Finally, the probable mechanism of anodic dissolution of RuO2-based electrode, has been proposed.
TY - JOUR
AU - Gajić-Krstajić, Lj.M.
AU - Trišović, T.Lj.
AU - Krstajić, Nedeljko V.
PY - 2004
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5401
AB - Electrochemical properties of RuO2-based electrode, particularly the oxygen evolution and anodic dissolution of RuO2 have been investigated in 0.5 mol dm-3 H2SO4 solution by means of polarization measurements and product analysis. It has been demonstrated that it is possible to determine very low concentration of dissolved ruthenium species (8 × 10-10 mol dm-3 Ru) by a sensitive spectrophotometric method based on the ruthenium-catalyzed ceric-arsenite reaction.Finally, the probable mechanism of anodic dissolution of RuO2-based electrode, has been proposed.
PB - Elsevier Ltd
T2 - Corrosion Science
T1 - Spectrophotometric study of the anodic corrosion of Ti/RuO2 electrode in acid sulfate solution
EP - 74
IS - 1
SP - 65
VL - 46
DO - 10.1016/S0010-938X(03)00111-2
ER -
@article{
author = "Gajić-Krstajić, Lj.M. and Trišović, T.Lj. and Krstajić, Nedeljko V.",
year = "2004",
abstract = "Electrochemical properties of RuO2-based electrode, particularly the oxygen evolution and anodic dissolution of RuO2 have been investigated in 0.5 mol dm-3 H2SO4 solution by means of polarization measurements and product analysis. It has been demonstrated that it is possible to determine very low concentration of dissolved ruthenium species (8 × 10-10 mol dm-3 Ru) by a sensitive spectrophotometric method based on the ruthenium-catalyzed ceric-arsenite reaction.Finally, the probable mechanism of anodic dissolution of RuO2-based electrode, has been proposed.",
publisher = "Elsevier Ltd",
journal = "Corrosion Science",
title = "Spectrophotometric study of the anodic corrosion of Ti/RuO2 electrode in acid sulfate solution",
pages = "74-65",
number = "1",
volume = "46",
doi = "10.1016/S0010-938X(03)00111-2"
}
Gajić-Krstajić, Lj.M., Trišović, T.Lj.,& Krstajić, N. V.. (2004). Spectrophotometric study of the anodic corrosion of Ti/RuO2 electrode in acid sulfate solution. in Corrosion Science
Elsevier Ltd., 46(1), 65-74.
https://doi.org/10.1016/S0010-938X(03)00111-2
Gajić-Krstajić L, Trišović T, Krstajić NV. Spectrophotometric study of the anodic corrosion of Ti/RuO2 electrode in acid sulfate solution. in Corrosion Science. 2004;46(1):65-74.
doi:10.1016/S0010-938X(03)00111-2 .
Gajić-Krstajić, Lj.M., Trišović, T.Lj., Krstajić, Nedeljko V., "Spectrophotometric study of the anodic corrosion of Ti/RuO2 electrode in acid sulfate solution" in Corrosion Science, 46, no. 1 (2004):65-74,
https://doi.org/10.1016/S0010-938X(03)00111-2 . .
