Methyl methacrylate and acrylamide crosslinked macroporous copolymers
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2004
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In this work the synthesis of a crosslinked macroporous copolymer was effected from methyl methacrylate and acrylamide. The synthesis process began with emulsion prepolymerization, followed by sol-gel copolymerization until a hard block was obtained. Determination of the properties of the obtained material was carried out by FTIR, mercury porosimetry, and SEM microscopy. The material was characterized by a porous structure with open pores. The macroporous copolymer obtained can be used for polymer-analog reactions and the transformation of amide and ester groups into acyl azide groups. It can be used as a hard inert support for the immobilization of enzymes, or other proteins, by condensation of acyl azide group on poly-mer with the free amino group from the base amino acid of enzyme/protein. For the immobilization of microorganisms it can be used by vacuum diffusion of microorganism suspension into the porous structure, without active group transformation reactions. With microorganism...s in the polymer pores, microorganism colonies form within the copolymer by microbial fermentation. (C) 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 387-395, 2004.
Ključne reči:
macroporous polymers / emulsion polymerization / crosslinking / carrier microorganism / enzyme immobilizationIzvor:
Journal of Applied Polymer Science, 2004, 91, 1, 387-395
DOI: 10.1002/app.13113
ISSN: 0021-8995
WoS: 000186915100054
Scopus: 2-s2.0-0348146298
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Nikolic, L AU - Skala, Dejan AU - Nikolić, Vladimir M. AU - Stamenkovic, J AU - Babić, Dragan AU - Ilic-Stojanovic, S PY - 2004 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5403 AB - In this work the synthesis of a crosslinked macroporous copolymer was effected from methyl methacrylate and acrylamide. The synthesis process began with emulsion prepolymerization, followed by sol-gel copolymerization until a hard block was obtained. Determination of the properties of the obtained material was carried out by FTIR, mercury porosimetry, and SEM microscopy. The material was characterized by a porous structure with open pores. The macroporous copolymer obtained can be used for polymer-analog reactions and the transformation of amide and ester groups into acyl azide groups. It can be used as a hard inert support for the immobilization of enzymes, or other proteins, by condensation of acyl azide group on poly-mer with the free amino group from the base amino acid of enzyme/protein. For the immobilization of microorganisms it can be used by vacuum diffusion of microorganism suspension into the porous structure, without active group transformation reactions. With microorganisms in the polymer pores, microorganism colonies form within the copolymer by microbial fermentation. (C) 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 387-395, 2004. T2 - Journal of Applied Polymer Science T1 - Methyl methacrylate and acrylamide crosslinked macroporous copolymers EP - 395 IS - 1 SP - 387 VL - 91 DO - 10.1002/app.13113 ER -
@article{ author = "Nikolic, L and Skala, Dejan and Nikolić, Vladimir M. and Stamenkovic, J and Babić, Dragan and Ilic-Stojanovic, S", year = "2004", abstract = "In this work the synthesis of a crosslinked macroporous copolymer was effected from methyl methacrylate and acrylamide. The synthesis process began with emulsion prepolymerization, followed by sol-gel copolymerization until a hard block was obtained. Determination of the properties of the obtained material was carried out by FTIR, mercury porosimetry, and SEM microscopy. The material was characterized by a porous structure with open pores. The macroporous copolymer obtained can be used for polymer-analog reactions and the transformation of amide and ester groups into acyl azide groups. It can be used as a hard inert support for the immobilization of enzymes, or other proteins, by condensation of acyl azide group on poly-mer with the free amino group from the base amino acid of enzyme/protein. For the immobilization of microorganisms it can be used by vacuum diffusion of microorganism suspension into the porous structure, without active group transformation reactions. With microorganisms in the polymer pores, microorganism colonies form within the copolymer by microbial fermentation. (C) 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 387-395, 2004.", journal = "Journal of Applied Polymer Science", title = "Methyl methacrylate and acrylamide crosslinked macroporous copolymers", pages = "395-387", number = "1", volume = "91", doi = "10.1002/app.13113" }
Nikolic, L., Skala, D., Nikolić, V. M., Stamenkovic, J., Babić, D.,& Ilic-Stojanovic, S.. (2004). Methyl methacrylate and acrylamide crosslinked macroporous copolymers. in Journal of Applied Polymer Science, 91(1), 387-395. https://doi.org/10.1002/app.13113
Nikolic L, Skala D, Nikolić VM, Stamenkovic J, Babić D, Ilic-Stojanovic S. Methyl methacrylate and acrylamide crosslinked macroporous copolymers. in Journal of Applied Polymer Science. 2004;91(1):387-395. doi:10.1002/app.13113 .
Nikolic, L, Skala, Dejan, Nikolić, Vladimir M., Stamenkovic, J, Babić, Dragan, Ilic-Stojanovic, S, "Methyl methacrylate and acrylamide crosslinked macroporous copolymers" in Journal of Applied Polymer Science, 91, no. 1 (2004):387-395, https://doi.org/10.1002/app.13113 . .