1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Crystal structure analysis of the title complex, (H3NC 3H6NH3)[Cu{C6H2(COO) 4}] ·2H2O, showed that the structure is built up from Cu(II) and tetradentate 1,2,4,5-benzenetetracarboxylate(4-) (btc) ions forming a 3D open-framework with two different channels extending parallel to the [110]/[1,-1,0] and [001] directions. The first, wider channels accommodate 1,3-propanediammonium cations, whereas the second ones are filled with H 2O molecules. The Cu(II) ions are in a tetrahedrally distorted square-planar environment consisting of four carboxylate O atoms from four different btc ligands. The four uncoordinated O atoms from the same carboxylate groups are placed around Cu(II) at longer distances (≈ 2.8 A), forming a distorted sphenoid. The complex crystallizes in the orthorhombic space group Cc2m with a = 8.887(1), b = 11.493(2), c = 16.457(3) Å, K= 1680.9(5) Å3 and Z=4. Final agreement indices are: R, = 0.0303 for 1012 reflections with 1 > 2σ(I), wR2 = 0.0493 for 1317 independent reflecti...ons and 123 refined parameters. The compound was also characterized by IR spectroscopy and TG/DSC analysis.
Кључне речи:
1,2,4,5-benzenetetracarboxylate ion / 1,3-propanediammonium ion / Copper(II); Crystal structure / Thermal properties / Transition metal complexesИзвор:
Journal of the Serbian Chemical Society, 2005, 70, 12, 1441-1450Издавач:
- Serbian Chemical Society
Финансирање / пројекти:
- This work was financially supported (Grant No. 1603) by the Ministry of Science and Enviromental Protection of the Republic of Serbia.
DOI: 10.2298/JSC0512441P
ISSN: 0352-5139
WoS: 000235782500008
Scopus: 2-s2.0-31544440728
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Poleti, Dejan AU - Karanović, Ljiljana PY - 2005 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5445 AB - Crystal structure analysis of the title complex, (H3NC 3H6NH3)[Cu{C6H2(COO) 4}] ·2H2O, showed that the structure is built up from Cu(II) and tetradentate 1,2,4,5-benzenetetracarboxylate(4-) (btc) ions forming a 3D open-framework with two different channels extending parallel to the [110]/[1,-1,0] and [001] directions. The first, wider channels accommodate 1,3-propanediammonium cations, whereas the second ones are filled with H 2O molecules. The Cu(II) ions are in a tetrahedrally distorted square-planar environment consisting of four carboxylate O atoms from four different btc ligands. The four uncoordinated O atoms from the same carboxylate groups are placed around Cu(II) at longer distances (≈ 2.8 A), forming a distorted sphenoid. The complex crystallizes in the orthorhombic space group Cc2m with a = 8.887(1), b = 11.493(2), c = 16.457(3) Å, K= 1680.9(5) Å3 and Z=4. Final agreement indices are: R, = 0.0303 for 1012 reflections with 1 > 2σ(I), wR2 = 0.0493 for 1317 independent reflections and 123 refined parameters. The compound was also characterized by IR spectroscopy and TG/DSC analysis. PB - Serbian Chemical Society T2 - Journal of the Serbian Chemical Society T1 - 1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure EP - 1450 IS - 12 SP - 1441 VL - 70 DO - 10.2298/JSC0512441P ER -
@article{ author = "Poleti, Dejan and Karanović, Ljiljana", year = "2005", abstract = "Crystal structure analysis of the title complex, (H3NC 3H6NH3)[Cu{C6H2(COO) 4}] ·2H2O, showed that the structure is built up from Cu(II) and tetradentate 1,2,4,5-benzenetetracarboxylate(4-) (btc) ions forming a 3D open-framework with two different channels extending parallel to the [110]/[1,-1,0] and [001] directions. The first, wider channels accommodate 1,3-propanediammonium cations, whereas the second ones are filled with H 2O molecules. The Cu(II) ions are in a tetrahedrally distorted square-planar environment consisting of four carboxylate O atoms from four different btc ligands. The four uncoordinated O atoms from the same carboxylate groups are placed around Cu(II) at longer distances (≈ 2.8 A), forming a distorted sphenoid. The complex crystallizes in the orthorhombic space group Cc2m with a = 8.887(1), b = 11.493(2), c = 16.457(3) Å, K= 1680.9(5) Å3 and Z=4. Final agreement indices are: R, = 0.0303 for 1012 reflections with 1 > 2σ(I), wR2 = 0.0493 for 1317 independent reflections and 123 refined parameters. The compound was also characterized by IR spectroscopy and TG/DSC analysis.", publisher = "Serbian Chemical Society", journal = "Journal of the Serbian Chemical Society", title = "1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure", pages = "1450-1441", number = "12", volume = "70", doi = "10.2298/JSC0512441P" }
Poleti, D.,& Karanović, L.. (2005). 1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure. in Journal of the Serbian Chemical Society Serbian Chemical Society., 70(12), 1441-1450. https://doi.org/10.2298/JSC0512441P
Poleti D, Karanović L. 1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure. in Journal of the Serbian Chemical Society. 2005;70(12):1441-1450. doi:10.2298/JSC0512441P .
Poleti, Dejan, Karanović, Ljiljana, "1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure" in Journal of the Serbian Chemical Society, 70, no. 12 (2005):1441-1450, https://doi.org/10.2298/JSC0512441P . .