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Uticaj temperature na elektrohemijsko taloženje disperznih taloga bakra

dc.creatorNikolić, Nebojša D.
dc.creatorPavlović, Ljubica
dc.creatorPavlović, Miomir
dc.creatorPopov, Konstantin I.
dc.date.accessioned2019-01-30T17:15:53Z
dc.date.accessioned2023-01-18T12:46:00Z
dc.date.available2019-01-30T17:15:53Z
dc.date.available2023-01-18T12:46:00Z
dc.date.issued2007
dc.identifier.issn0352-5139
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/5486
dc.description.abstractThe effect of temperature on the electrodeposition of copper at overpotentials belonging to the plateau of the limiting diffusion current density and higher was examined by the determination of the average current efficiency of hydrogen evolution and by scanning electron microscopic (SEM) analysis of the morphology of the formed copper deposits. Increasing the temperature of the solution led to a shift of both the beginning and the end of the plateau of the limiting diffusion current density towards lower electrodeposition overpotentials. Also, higher temperatures led to the formation of morphological forms of copper deposits characteristic for electrodeposition of copper at some higher overpotentials. The unexpected trend in the development of copper structures electrodeposited at an overpotential of 800 mV is discussed in terms of the effect of temperature on the viscosity and surface tension of the electroplating solution.en
dc.description.abstractUticaj temperature na elektrohemijsko taloženje bakra na prenapetostima koje pripadaju platoima granične difuzione gustine struje, kao i na višim prenapetostima je ispitan određivanjem srednjeg iskorišćenja struje reakcije izdvajanja vodonika i analizom morfologija taloga bakra tehnikom skenirajuće elektronske mikroskopije. Povećanje temperature rastvora dovelo je do pomeranja i početka i kraja platoa granične difuzione gustine struje ka nižim prenapetostima. Takođe, povećanje temperature dovelo je do formiranja morfoloških formi taloga bakra karakterističnih za elektrohemijsko taloženje na nekim višim prenapetostima. Neočekivani trend u razvoju struktura bakra dobijenih na prenapetosti od 800 mV je bio diskutovan na osnovu uticaja temperature na viskoznost i površinski napon rastvora za elektrohemijsko taloženje bakra.sr
dc.publisherSerbian Chemical Society
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142032/RS//
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceJournal of the Serbian Chemical Society
dc.subjectelectrodepositionen
dc.subjectcopperen
dc.subjecthydrogen evolutionen
dc.subjecttemperatureen
dc.subjectviscosityen
dc.subjectsurface tensionen
dc.titleEffect of temperature on the electrodeposition of disperse copper depositsen
dc.titleUticaj temperature na elektrohemijsko taloženje disperznih taloga bakrasr
dc.typearticle
dc.rights.licenseBY-NC-ND
dc.citation.epage1381
dc.citation.issue12
dc.citation.other72(12): 1369-1381
dc.citation.rankM23
dc.citation.spage1369
dc.citation.volume72
dc.identifier.doi10.2298/JSC0712369N
dc.identifier.fulltexthttp://TechnoRep.tmf.bg.ac.rs/bitstream/id/14300/329.pdf
dc.identifier.scopus2-s2.0-36949035155
dc.identifier.wos000252412100021
dc.type.versionpublishedVersion


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