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Contribution to the Serbian coal ranking and fly ash characterization using Pb isotopic ratio

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2022
6_MME_931_P.pdf (627.0Kb)
Authors
Đolić, Maja
Ćujić, Mirjana
Stanišić, Tijana
Čičkarić, Dragana
Ristić, Mirjana
Perić Grujić, Aleksandra
Article (Published version)
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Abstract
The Republic of Serbia generates the majority of its electricity at the thermal power plants (TE) Nikola Tesla, Kolubara, and Kostolac. Coal is extracted from the Kolubara basin, which produces approximately 70% of lignite (an average of 30 million tons per year), and the Kostolac basin, which produces 30% of lignite. Ash, fly ash, and slag are examples of coal combustion residues. Because of the high content of potentially hazardous elements such as As, Pb, Cd, and Cr, environmental pollution with ash and fly ash has been extensively researched. Stable isotopes of lead can be used to trace lead sources. It is possible to monitor the presence, transformation pathways, and environmental impact of Pb by determining its isotopic composition in coal and fly ash. For the first time, the isotopic composition of selected coal samples from the Kolubara and Kostolac mines, as well as fly ash from the Kolubara (A and B), Kostolac (A and B), and Nikola Tesla (TENT A3, A2, B2) thermal power plants..., was investigated in this study. The obtained data for 206Pb/207Pb in coal serve as the foundation for ranking domestic coals, whereas the isotopic ratios 206Pb/207Pb and 208Pb/207Pb  in fly ash can be used to monitor and control lead pollution from investigated sources.

Keywords:
coal combustion / emission / Pb isotopic fingerprint / pollution
Source:
Metallurgical and Materials Engineering, 2022, 28, 4, 675-684
Funding / projects:
  • SIW4SE - Serbian Industrial Waste towards Sustainable Environment: Resource of Strategic Elements and Removal Agent for Pollutants (RS-7743343)

DOI: 10.56801/MME931

ISSN: 2812-9105

Scopus: 2-s2.0-85145861233
[ Google Scholar ]
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5518
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Đolić, Maja
AU  - Ćujić, Mirjana
AU  - Stanišić, Tijana
AU  - Čičkarić, Dragana
AU  - Ristić, Mirjana
AU  - Perić Grujić, Aleksandra
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5518
AB  - The Republic of Serbia generates the majority of its electricity at the thermal power plants (TE) Nikola Tesla, Kolubara, and Kostolac. Coal is extracted from the Kolubara basin, which produces approximately 70% of lignite (an average of 30 million tons per year), and the Kostolac basin, which produces 30% of lignite. Ash, fly ash, and slag are examples of coal combustion residues. Because of the high content of potentially hazardous elements such as As, Pb, Cd, and Cr, environmental pollution with ash and fly ash has been extensively researched. Stable isotopes of lead can be used to trace lead sources. It is possible to monitor the presence, transformation pathways, and environmental impact of Pb by determining its isotopic composition in coal and fly ash. For the first time, the isotopic composition of selected coal samples from the Kolubara and Kostolac mines, as well as fly ash from the Kolubara (A and B), Kostolac (A and B), and Nikola Tesla (TENT A3, A2, B2) thermal power plants, was investigated in this study. The obtained data for 206Pb/207Pb in coal serve as the foundation for ranking domestic coals, whereas the isotopic ratios 206Pb/207Pb and 208Pb/207Pb  in fly ash can be used to monitor and control lead pollution from investigated sources.
T2  - Metallurgical and Materials Engineering
T1  - Contribution to the Serbian coal ranking and fly ash characterization using Pb isotopic ratio
EP  - 684
IS  - 4
SP  - 675
VL  - 28
DO  - 10.56801/MME931
ER  - 
@article{
author = "Đolić, Maja and Ćujić, Mirjana and Stanišić, Tijana and Čičkarić, Dragana and Ristić, Mirjana and Perić Grujić, Aleksandra",
year = "2022",
abstract = "The Republic of Serbia generates the majority of its electricity at the thermal power plants (TE) Nikola Tesla, Kolubara, and Kostolac. Coal is extracted from the Kolubara basin, which produces approximately 70% of lignite (an average of 30 million tons per year), and the Kostolac basin, which produces 30% of lignite. Ash, fly ash, and slag are examples of coal combustion residues. Because of the high content of potentially hazardous elements such as As, Pb, Cd, and Cr, environmental pollution with ash and fly ash has been extensively researched. Stable isotopes of lead can be used to trace lead sources. It is possible to monitor the presence, transformation pathways, and environmental impact of Pb by determining its isotopic composition in coal and fly ash. For the first time, the isotopic composition of selected coal samples from the Kolubara and Kostolac mines, as well as fly ash from the Kolubara (A and B), Kostolac (A and B), and Nikola Tesla (TENT A3, A2, B2) thermal power plants, was investigated in this study. The obtained data for 206Pb/207Pb in coal serve as the foundation for ranking domestic coals, whereas the isotopic ratios 206Pb/207Pb and 208Pb/207Pb  in fly ash can be used to monitor and control lead pollution from investigated sources.",
journal = "Metallurgical and Materials Engineering",
title = "Contribution to the Serbian coal ranking and fly ash characterization using Pb isotopic ratio",
pages = "684-675",
number = "4",
volume = "28",
doi = "10.56801/MME931"
}
Đolić, M., Ćujić, M., Stanišić, T., Čičkarić, D., Ristić, M.,& Perić Grujić, A.. (2022). Contribution to the Serbian coal ranking and fly ash characterization using Pb isotopic ratio. in Metallurgical and Materials Engineering, 28(4), 675-684.
https://doi.org/10.56801/MME931
Đolić M, Ćujić M, Stanišić T, Čičkarić D, Ristić M, Perić Grujić A. Contribution to the Serbian coal ranking and fly ash characterization using Pb isotopic ratio. in Metallurgical and Materials Engineering. 2022;28(4):675-684.
doi:10.56801/MME931 .
Đolić, Maja, Ćujić, Mirjana, Stanišić, Tijana, Čičkarić, Dragana, Ristić, Mirjana, Perić Grujić, Aleksandra, "Contribution to the Serbian coal ranking and fly ash characterization using Pb isotopic ratio" in Metallurgical and Materials Engineering, 28, no. 4 (2022):675-684,
https://doi.org/10.56801/MME931 . .

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