Mechanochemistry represents an alternative route in synthesis of nanomaterials. Mechanochemical routes are attractive because of their simplicity, flexibility, and ability to prepare materials by solid state reactions at room temperature. The aim of this work is the mechanochemical synthesis of nanostructured titanium oxides of different composition starting from mixtures of Ti and TiO2, TiO and TiO2 or Ti 2O3 and TiO2. Emphasis is on the Magneli phases Ti4O7 and Ti5O9 because their mixture is commercially known as EBONEX material. The materials prepared were characterized by XRPD, TG/DTA analysis, SEM and optical microscopy. Titanium monoxide and several Magneli oxides, Ti4O7, Ti 5O9 and Ti6O11, are successsfully prepared. The results are very interesting because the EBONEX materials were prepared at lower than usual temperature, which would decrease the effective cost of production.
TY - JOUR
AU - Veljković, Ivana
AU - Poleti, Dejan
AU - Zdujić, Miodrag
AU - Karanović, Ljiljana
PY - 2009
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5534
AB - Mechanochemistry represents an alternative route in synthesis of nanomaterials. Mechanochemical routes are attractive because of their simplicity, flexibility, and ability to prepare materials by solid state reactions at room temperature. The aim of this work is the mechanochemical synthesis of nanostructured titanium oxides of different composition starting from mixtures of Ti and TiO2, TiO and TiO2 or Ti 2O3 and TiO2. Emphasis is on the Magneli phases Ti4O7 and Ti5O9 because their mixture is commercially known as EBONEX material. The materials prepared were characterized by XRPD, TG/DTA analysis, SEM and optical microscopy. Titanium monoxide and several Magneli oxides, Ti4O7, Ti 5O9 and Ti6O11, are successsfully prepared. The results are very interesting because the EBONEX materials were prepared at lower than usual temperature, which would decrease the effective cost of production.
PB - Belgrade : Association of the Chemical Engineers of Serbia
T2 - Hemijska industrija
T1 - Mechanochemistry of titanium oxides
EP - 251
IS - 3
SP - 247
VL - 63
DO - 10.2298/HEMIND0903247V
UR - https://hdl.handle.net/21.15107/rcub_dais_3458
ER -
@article{
author = "Veljković, Ivana and Poleti, Dejan and Zdujić, Miodrag and Karanović, Ljiljana",
year = "2009",
abstract = "Mechanochemistry represents an alternative route in synthesis of nanomaterials. Mechanochemical routes are attractive because of their simplicity, flexibility, and ability to prepare materials by solid state reactions at room temperature. The aim of this work is the mechanochemical synthesis of nanostructured titanium oxides of different composition starting from mixtures of Ti and TiO2, TiO and TiO2 or Ti 2O3 and TiO2. Emphasis is on the Magneli phases Ti4O7 and Ti5O9 because their mixture is commercially known as EBONEX material. The materials prepared were characterized by XRPD, TG/DTA analysis, SEM and optical microscopy. Titanium monoxide and several Magneli oxides, Ti4O7, Ti 5O9 and Ti6O11, are successsfully prepared. The results are very interesting because the EBONEX materials were prepared at lower than usual temperature, which would decrease the effective cost of production.",
publisher = "Belgrade : Association of the Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Mechanochemistry of titanium oxides",
pages = "251-247",
number = "3",
volume = "63",
doi = "10.2298/HEMIND0903247V",
url = "https://hdl.handle.net/21.15107/rcub_dais_3458"
}
Veljković, I., Poleti, D., Zdujić, M.,& Karanović, L.. (2009). Mechanochemistry of titanium oxides. in Hemijska industrija
Belgrade : Association of the Chemical Engineers of Serbia., 63(3), 247-251.
https://doi.org/10.2298/HEMIND0903247V
https://hdl.handle.net/21.15107/rcub_dais_3458
Veljković I, Poleti D, Zdujić M, Karanović L. Mechanochemistry of titanium oxides. in Hemijska industrija. 2009;63(3):247-251.
doi:10.2298/HEMIND0903247V
https://hdl.handle.net/21.15107/rcub_dais_3458 .
