During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail.
TY - JOUR
AU - Šutović, Sabina
AU - Karanović, Ljiljana
AU - Poleti, Dejan
PY - 2009
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5547
AB - During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail.
PB - International Union of Crystallography
T2 - Acta Crystallographica Section C: Crystal Structure Communications
T1 - Reinvestigation of Sr2 [Cu(OH)6]
EP - i51
IS - 8
SP - i48
VL - 65
DO - 10.1107/S0108270109021519
ER -
@article{
author = "Šutović, Sabina and Karanović, Ljiljana and Poleti, Dejan",
year = "2009",
abstract = "During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail.",
publisher = "International Union of Crystallography",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
title = "Reinvestigation of Sr2 [Cu(OH)6]",
pages = "i51-i48",
number = "8",
volume = "65",
doi = "10.1107/S0108270109021519"
}
Šutović, S., Karanović, L.,& Poleti, D.. (2009). Reinvestigation of Sr2 [Cu(OH)6]. in Acta Crystallographica Section C: Crystal Structure Communications
International Union of Crystallography., 65(8), i48-i51.
https://doi.org/10.1107/S0108270109021519
Šutović S, Karanović L, Poleti D. Reinvestigation of Sr2 [Cu(OH)6]. in Acta Crystallographica Section C: Crystal Structure Communications. 2009;65(8):i48-i51.
doi:10.1107/S0108270109021519 .
