The kinetics of Ca(OH)2-catalyzed methanolysis of sunflower oil was studied at a moderate temperature (60 °C), a methanol-to-oil molar ratio (6:1) and different catalyst amounts (from 1% to 10% based on oil weight). The methanolysis process was shown to involve the initial triglyceride (TG) mass transfer controlled region, followed by the chemical reaction controlled region in the latter period. The TG mass transfer limitation was caused by the low available active specific catalyst surface due to the high adsorbed methanol concentration. Both the TG mass transfer and chemical reaction rates increased with increasing the catalyst amount.
Keywords:
Biodiesel / Calcium hydroxide / Kinetics / Mass transfer / Methanolysis
TY - JOUR
AU - Stamenković, Olivera S.
AU - Veljković, Vlada B.
AU - Todorović, Zoran B.
AU - Lazić, Miodrag L.
AU - Banković-Ilić, Ivana B.
AU - Skala, Dejan U.
PY - 2010
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5612
AB - The kinetics of Ca(OH)2-catalyzed methanolysis of sunflower oil was studied at a moderate temperature (60 °C), a methanol-to-oil molar ratio (6:1) and different catalyst amounts (from 1% to 10% based on oil weight). The methanolysis process was shown to involve the initial triglyceride (TG) mass transfer controlled region, followed by the chemical reaction controlled region in the latter period. The TG mass transfer limitation was caused by the low available active specific catalyst surface due to the high adsorbed methanol concentration. Both the TG mass transfer and chemical reaction rates increased with increasing the catalyst amount.
PB - Elsevier
T2 - Bioresource Technology
T1 - Modeling the kinetics of calcium hydroxide catalyzed methanolysis of sunflower oil
EP - 4430
IS - 12
SP - 4423
VL - 101
DO - 10.1016/j.biortech.2010.01.109
ER -
@article{
author = "Stamenković, Olivera S. and Veljković, Vlada B. and Todorović, Zoran B. and Lazić, Miodrag L. and Banković-Ilić, Ivana B. and Skala, Dejan U.",
year = "2010",
abstract = "The kinetics of Ca(OH)2-catalyzed methanolysis of sunflower oil was studied at a moderate temperature (60 °C), a methanol-to-oil molar ratio (6:1) and different catalyst amounts (from 1% to 10% based on oil weight). The methanolysis process was shown to involve the initial triglyceride (TG) mass transfer controlled region, followed by the chemical reaction controlled region in the latter period. The TG mass transfer limitation was caused by the low available active specific catalyst surface due to the high adsorbed methanol concentration. Both the TG mass transfer and chemical reaction rates increased with increasing the catalyst amount.",
publisher = "Elsevier",
journal = "Bioresource Technology",
title = "Modeling the kinetics of calcium hydroxide catalyzed methanolysis of sunflower oil",
pages = "4430-4423",
number = "12",
volume = "101",
doi = "10.1016/j.biortech.2010.01.109"
}
Stamenković, O. S., Veljković, V. B., Todorović, Z. B., Lazić, M. L., Banković-Ilić, I. B.,& Skala, D. U.. (2010). Modeling the kinetics of calcium hydroxide catalyzed methanolysis of sunflower oil. in Bioresource Technology
Elsevier., 101(12), 4423-4430.
https://doi.org/10.1016/j.biortech.2010.01.109
Stamenković OS, Veljković VB, Todorović ZB, Lazić ML, Banković-Ilić IB, Skala DU. Modeling the kinetics of calcium hydroxide catalyzed methanolysis of sunflower oil. in Bioresource Technology. 2010;101(12):4423-4430.
doi:10.1016/j.biortech.2010.01.109 .
Stamenković, Olivera S., Veljković, Vlada B., Todorović, Zoran B., Lazić, Miodrag L., Banković-Ilić, Ivana B., Skala, Dejan U., "Modeling the kinetics of calcium hydroxide catalyzed methanolysis of sunflower oil" in Bioresource Technology, 101, no. 12 (2010):4423-4430,
https://doi.org/10.1016/j.biortech.2010.01.109 . .
