The effects of common precursors used in the synthesis of CeO2 nanopowders were investigated, and the structural and spectral properties of the resulting products were compared. Two cerium (III) salts, i.e., Ce(NO3)(3)center dot 6H(2)O and CeCl3 center dot 7H(2)O, and two cerium (IV) salts, i.e., Ce (SO4)(2)center dot 4H(2)O and (NH4)(2)Ce(NO3)(6) were applied. The proposed procedures for the CeO2 preparations were realizdd using the same hydrothermal treatment conditions. The products were characterized using X-ray powder diffraction (XRD) and thermogravimetric (TG) analysis, and the morphology was determined using scanning (SEM) and transmission electron microscopy (TEM). The spectral properties of the obtained nanopowders were characterized by FT-IR, Raman scattering and UV-vis spectroscopy. The results revealed the influence of the precursors on the crystallinity, crystallite size, band gap energy, morphology and purity of the synthesized samples.
Keywords:
Spectroscopy / Powders: chemical preparation / Optical properties / CeO2
TY - JOUR
AU - Zdravković, Jelena
AU - Simović, Bojana
AU - Golubović, Aleksandar
AU - Poleti, Dejan
AU - Veljković, Ivana
AU - Šćepanović, Maja
AU - Branković, Goran
PY - 2015
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5754
AB - The effects of common precursors used in the synthesis of CeO2 nanopowders were investigated, and the structural and spectral properties of the resulting products were compared. Two cerium (III) salts, i.e., Ce(NO3)(3)center dot 6H(2)O and CeCl3 center dot 7H(2)O, and two cerium (IV) salts, i.e., Ce (SO4)(2)center dot 4H(2)O and (NH4)(2)Ce(NO3)(6) were applied. The proposed procedures for the CeO2 preparations were realizdd using the same hydrothermal treatment conditions. The products were characterized using X-ray powder diffraction (XRD) and thermogravimetric (TG) analysis, and the morphology was determined using scanning (SEM) and transmission electron microscopy (TEM). The spectral properties of the obtained nanopowders were characterized by FT-IR, Raman scattering and UV-vis spectroscopy. The results revealed the influence of the precursors on the crystallinity, crystallite size, band gap energy, morphology and purity of the synthesized samples.
PB - Elsevier Sci Ltd, Oxford
T2 - Ceramics International
T1 - Comparative study of CeO2 nanopowders obtained by the hydrothermal method from various precursors
EP - 1979
IS - 2
SP - 1970
VL - 41
DO - 10.1016/j.ceramint.2014.08.122
ER -
@article{
author = "Zdravković, Jelena and Simović, Bojana and Golubović, Aleksandar and Poleti, Dejan and Veljković, Ivana and Šćepanović, Maja and Branković, Goran",
year = "2015",
abstract = "The effects of common precursors used in the synthesis of CeO2 nanopowders were investigated, and the structural and spectral properties of the resulting products were compared. Two cerium (III) salts, i.e., Ce(NO3)(3)center dot 6H(2)O and CeCl3 center dot 7H(2)O, and two cerium (IV) salts, i.e., Ce (SO4)(2)center dot 4H(2)O and (NH4)(2)Ce(NO3)(6) were applied. The proposed procedures for the CeO2 preparations were realizdd using the same hydrothermal treatment conditions. The products were characterized using X-ray powder diffraction (XRD) and thermogravimetric (TG) analysis, and the morphology was determined using scanning (SEM) and transmission electron microscopy (TEM). The spectral properties of the obtained nanopowders were characterized by FT-IR, Raman scattering and UV-vis spectroscopy. The results revealed the influence of the precursors on the crystallinity, crystallite size, band gap energy, morphology and purity of the synthesized samples.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Comparative study of CeO2 nanopowders obtained by the hydrothermal method from various precursors",
pages = "1979-1970",
number = "2",
volume = "41",
doi = "10.1016/j.ceramint.2014.08.122"
}
Zdravković, J., Simović, B., Golubović, A., Poleti, D., Veljković, I., Šćepanović, M.,& Branković, G.. (2015). Comparative study of CeO2 nanopowders obtained by the hydrothermal method from various precursors. in Ceramics International
Elsevier Sci Ltd, Oxford., 41(2), 1970-1979.
https://doi.org/10.1016/j.ceramint.2014.08.122
Zdravković J, Simović B, Golubović A, Poleti D, Veljković I, Šćepanović M, Branković G. Comparative study of CeO2 nanopowders obtained by the hydrothermal method from various precursors. in Ceramics International. 2015;41(2):1970-1979.
doi:10.1016/j.ceramint.2014.08.122 .
Zdravković, Jelena, Simović, Bojana, Golubović, Aleksandar, Poleti, Dejan, Veljković, Ivana, Šćepanović, Maja, Branković, Goran, "Comparative study of CeO2 nanopowders obtained by the hydrothermal method from various precursors" in Ceramics International, 41, no. 2 (2015):1970-1979,
https://doi.org/10.1016/j.ceramint.2014.08.122 . .
