Biocomposite membranes of highly methylated pectin and mesoporous silica SBA-15
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2014
Authors
Nešić, Aleksandra
Kokunešoski, Maja
Ilić, Svetlana M.

Gordić, Milan V.

Ostojić, Sanja
Micić, Darko M.
Veličković, Sava J.
Article

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Manufacturing of synthetic composites consumes huge energy and their disposal at the end of the life cycle is very difficult since there is virtually no recycling option. Therefore, biocomposite materials have recently received considerable attention in academic research and industrial application compared to the synthetic composite materials due biodegradability, nontoxicity and economical point of view. Biocomposite membranes of highly methylated pectin and SBA-15, a form of mesoporous silica, were prepared by membrane casting. The amount of SBA-15 was 10%, 20% and 30% by membrane mass. These membranes were characterized by optical microscopy, FTIR, XRD, thermogravimetry, mechanical analysis and swelling in water, HCl, NaOH and methanol. The incorporation of SBA-15 in pectin matrix enhanced the stability of these membranes in all tested solutions, compared to the pure pectin membranes. The pectin/SBA photomicrographs contain rod-like domains which indicate the presence of SBA-15 in m...embrane. Mechanical analysis proves that incorporation of SBA-15 enhances the elasticity and tensile strength of pectin membranes. Thermogravimety in nitrogen has shown that the presence of SBA-15 in the membranes increased the onset temperatures of pectin degradation. The novel composite material represents promising way for practical membrane application. (C) 2014 Elsevier Ltd. All rights reserved.
Keywords:
Polymer-matrix composites (PMCs) / Thermal properties / Mechanical propertiesSource:
Composites: Part B: Engineering, 2014, 64, 162-167Funding / projects:
- Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-45012)
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-43009)
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
DOI: 10.1016/j.compositesb.2014.04.019
ISSN: 1359-8368; 1879-1069
WoS: 000338407800018
Scopus: 2-s2.0-84901001829
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Nešić, Aleksandra AU - Kokunešoski, Maja AU - Ilić, Svetlana M. AU - Gordić, Milan V. AU - Ostojić, Sanja AU - Micić, Darko M. AU - Veličković, Sava J. PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5757 AB - Manufacturing of synthetic composites consumes huge energy and their disposal at the end of the life cycle is very difficult since there is virtually no recycling option. Therefore, biocomposite materials have recently received considerable attention in academic research and industrial application compared to the synthetic composite materials due biodegradability, nontoxicity and economical point of view. Biocomposite membranes of highly methylated pectin and SBA-15, a form of mesoporous silica, were prepared by membrane casting. The amount of SBA-15 was 10%, 20% and 30% by membrane mass. These membranes were characterized by optical microscopy, FTIR, XRD, thermogravimetry, mechanical analysis and swelling in water, HCl, NaOH and methanol. The incorporation of SBA-15 in pectin matrix enhanced the stability of these membranes in all tested solutions, compared to the pure pectin membranes. The pectin/SBA photomicrographs contain rod-like domains which indicate the presence of SBA-15 in membrane. Mechanical analysis proves that incorporation of SBA-15 enhances the elasticity and tensile strength of pectin membranes. Thermogravimety in nitrogen has shown that the presence of SBA-15 in the membranes increased the onset temperatures of pectin degradation. The novel composite material represents promising way for practical membrane application. (C) 2014 Elsevier Ltd. All rights reserved. T2 - Composites: Part B: Engineering T1 - Biocomposite membranes of highly methylated pectin and mesoporous silica SBA-15 EP - 167 SP - 162 VL - 64 DO - 10.1016/j.compositesb.2014.04.019 ER -
@article{ author = "Nešić, Aleksandra and Kokunešoski, Maja and Ilić, Svetlana M. and Gordić, Milan V. and Ostojić, Sanja and Micić, Darko M. and Veličković, Sava J.", year = "2014", abstract = "Manufacturing of synthetic composites consumes huge energy and their disposal at the end of the life cycle is very difficult since there is virtually no recycling option. Therefore, biocomposite materials have recently received considerable attention in academic research and industrial application compared to the synthetic composite materials due biodegradability, nontoxicity and economical point of view. Biocomposite membranes of highly methylated pectin and SBA-15, a form of mesoporous silica, were prepared by membrane casting. The amount of SBA-15 was 10%, 20% and 30% by membrane mass. These membranes were characterized by optical microscopy, FTIR, XRD, thermogravimetry, mechanical analysis and swelling in water, HCl, NaOH and methanol. The incorporation of SBA-15 in pectin matrix enhanced the stability of these membranes in all tested solutions, compared to the pure pectin membranes. The pectin/SBA photomicrographs contain rod-like domains which indicate the presence of SBA-15 in membrane. Mechanical analysis proves that incorporation of SBA-15 enhances the elasticity and tensile strength of pectin membranes. Thermogravimety in nitrogen has shown that the presence of SBA-15 in the membranes increased the onset temperatures of pectin degradation. The novel composite material represents promising way for practical membrane application. (C) 2014 Elsevier Ltd. All rights reserved.", journal = "Composites: Part B: Engineering", title = "Biocomposite membranes of highly methylated pectin and mesoporous silica SBA-15", pages = "167-162", volume = "64", doi = "10.1016/j.compositesb.2014.04.019" }
Nešić, A., Kokunešoski, M., Ilić, S. M., Gordić, M. V., Ostojić, S., Micić, D. M.,& Veličković, S. J.. (2014). Biocomposite membranes of highly methylated pectin and mesoporous silica SBA-15. in Composites: Part B: Engineering, 64, 162-167. https://doi.org/10.1016/j.compositesb.2014.04.019
Nešić A, Kokunešoski M, Ilić SM, Gordić MV, Ostojić S, Micić DM, Veličković SJ. Biocomposite membranes of highly methylated pectin and mesoporous silica SBA-15. in Composites: Part B: Engineering. 2014;64:162-167. doi:10.1016/j.compositesb.2014.04.019 .
Nešić, Aleksandra, Kokunešoski, Maja, Ilić, Svetlana M., Gordić, Milan V., Ostojić, Sanja, Micić, Darko M., Veličković, Sava J., "Biocomposite membranes of highly methylated pectin and mesoporous silica SBA-15" in Composites: Part B: Engineering, 64 (2014):162-167, https://doi.org/10.1016/j.compositesb.2014.04.019 . .