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dc.creatorTasić, Marija B.
dc.creatorMiladinović, Marija R.
dc.creatorStamenković, Olivera S.
dc.creatorVeljković, Vlada B.
dc.creatorSkala, Dejan U.
dc.date.accessioned2023-02-02T13:12:05Z
dc.date.available2023-02-02T13:12:05Z
dc.date.issued2015
dc.identifier.issn0930-7516
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/5763
dc.description.abstractThe kinetic model originally developed for quicklime-catalyzed methanolysis of sunflower oil was tested for another three calcium-based catalysts, namely, neat CaO, Ca(OH)2, and CaO·ZnO. This model includes the changing reaction mechanism and the triacylglycerol (TAG) mass transfer. The applicability and generalization capability of this model for heterogeneous methanolysis reaction catalyzed by calcium-based catalysts was evaluated. As indicated by the high coefficient of determination and the relatively small mean relative percentage deviation, the model was a reliable predictor of the time variation of TAG conversion degree in the sunflower oil methanolysis over all four calcium-based catalysts within the ranges of the reaction conditions applied. This model is recommended in general for describing the kinetics of sunflower oil methanolysis over calcium-based catalysts.The kinetic model originally developed for quicklime-catalyzed methanolysis of sunflower oil was tested for another three calcium-based catalysts, namely, neat CaO, Ca(OH)2, and CaO·ZnO. This model includes the changing reaction mechanism and the triacylglycerol (TAG) mass transfer. The applicability and generalization capability of this model for heterogeneous methanolysis reaction catalyzed by calcium-based catalysts was evaluated. As indicated by the high coefficient of determination and the relatively small mean relative percentage deviation, the model was a reliable predictor of the time variation of TAG conversion degree in the sunflower oil methanolysis over all four calcium-based catalysts within the ranges of the reaction conditions applied. This model is recommended in general for describing the kinetics of sunflower oil methanolysis over calcium-based catalysts.sr
dc.language.isoensr
dc.publisherWiley-VCH Verlagsr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//
dc.rightsrestrictedAccesssr
dc.sourceChemical Engineering and Technologysr
dc.subjectBiodieselsr
dc.subjectCalcium oxidesr
dc.subjectCalcium-based catalystssr
dc.subjectKineticssr
dc.subjectMethanolysissr
dc.titleKinetic Modeling of Sunflower Oil Methanolysis Catalyzed by Calcium-Based Catalystssr
dc.typearticlesr
dc.rights.licenseARRsr
dc.citation.epage1556
dc.citation.issue9
dc.citation.rankM21
dc.citation.spage1550
dc.citation.volume38
dc.identifier.doi10.1002/ceat.201500076
dc.identifier.scopus2-s2.0-84939863620
dc.identifier.wos000360370200006
dc.type.versionpublishedVersionsr


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Приказ основних података о документу