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Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo alloy

Elektrohemijska oksidacija ugljen-monoksida - od monokristala platine do katalizatora za niskotemperaturne gorivne galvanske spregove - II deo: Elektrohemijska oksidacija H2, CO I H2/CO smešama okarakterisanim PtMo legurama

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2003
0352-51390303191G.pdf (157.8Kb)
Authors
Grgur, Branimir
Marković, Nenad M.
Ross, Philip N.Jr.
Article (Published version)
Metadata
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Abstract
The oxidation of hydrogen and hydrogen–carbon monoxide mixture has been investigated on well-characterized metallurgically prepared platinum–molybdenum (PtMo) alloys. It was concluded that the optimum surface concentration of molybdenum is near 23 mol.%. Based on experimentally determined parameters and simulations, the mechanism of the oxidation of CO/H2 mixtures is discussed.
Ispitivana je oksidacija vodonika i njegovih smeša sa ugljen-monoksidom na površinski okarakterisanim platina–molibden legurama pripremljenim metalurškim tretmanom. Zaključeno je da je optimalna površinska koncentracija oko 23 mol.% molibdena. Na osnovu eksperimentalno određenih parametara i simulacije diskutovan je mehanizam oksidacije CO/H2 smeša.
Keywords:
fuel cell / anode / platinum / molybdenum / hydrogen / carbon monoxide
Source:
Journal of the Serbian Chemical Society, 2003, 68, 3, 191-205
Publisher:
  • Serbian Chemical Society, Belgrade

ISSN: 0352-5139

WoS: 000181865100005

Scopus: 2-s2.0-0038042284
[ Google Scholar ]
11
8
Handle
https://hdl.handle.net/21.15107/rcub_technorep_576
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/576
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Grgur, Branimir
AU  - Marković, Nenad M.
AU  - Ross, Philip N.Jr.
PY  - 2003
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/576
AB  - The oxidation of hydrogen and hydrogen–carbon monoxide mixture has been investigated on well-characterized metallurgically prepared platinum–molybdenum (PtMo) alloys. It was concluded that the optimum surface concentration of molybdenum is near 23 mol.%. Based on experimentally determined parameters and simulations, the mechanism of the oxidation of CO/H2 mixtures is discussed.
AB  - Ispitivana je oksidacija vodonika i njegovih smeša sa ugljen-monoksidom na površinski okarakterisanim platina–molibden legurama pripremljenim metalurškim tretmanom. Zaključeno je da je optimalna površinska koncentracija oko 23 mol.% molibdena. Na osnovu eksperimentalno određenih parametara i simulacije diskutovan je mehanizam oksidacije CO/H2 smeša.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo alloy
T1  - Elektrohemijska oksidacija ugljen-monoksida - od monokristala platine do katalizatora za niskotemperaturne gorivne galvanske spregove - II deo: Elektrohemijska oksidacija H2, CO I H2/CO smešama okarakterisanim PtMo legurama
EP  - 205
IS  - 3
SP  - 191
VL  - 68
UR  - https://hdl.handle.net/21.15107/rcub_technorep_576
ER  - 
@article{
author = "Grgur, Branimir and Marković, Nenad M. and Ross, Philip N.Jr.",
year = "2003",
abstract = "The oxidation of hydrogen and hydrogen–carbon monoxide mixture has been investigated on well-characterized metallurgically prepared platinum–molybdenum (PtMo) alloys. It was concluded that the optimum surface concentration of molybdenum is near 23 mol.%. Based on experimentally determined parameters and simulations, the mechanism of the oxidation of CO/H2 mixtures is discussed., Ispitivana je oksidacija vodonika i njegovih smeša sa ugljen-monoksidom na površinski okarakterisanim platina–molibden legurama pripremljenim metalurškim tretmanom. Zaključeno je da je optimalna površinska koncentracija oko 23 mol.% molibdena. Na osnovu eksperimentalno određenih parametara i simulacije diskutovan je mehanizam oksidacije CO/H2 smeša.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo alloy, Elektrohemijska oksidacija ugljen-monoksida - od monokristala platine do katalizatora za niskotemperaturne gorivne galvanske spregove - II deo: Elektrohemijska oksidacija H2, CO I H2/CO smešama okarakterisanim PtMo legurama",
pages = "205-191",
number = "3",
volume = "68",
url = "https://hdl.handle.net/21.15107/rcub_technorep_576"
}
Grgur, B., Marković, N. M.,& Ross, P. N.Jr.. (2003). Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo alloy. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 68(3), 191-205.
https://hdl.handle.net/21.15107/rcub_technorep_576
Grgur B, Marković NM, Ross PN. Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo alloy. in Journal of the Serbian Chemical Society. 2003;68(3):191-205.
https://hdl.handle.net/21.15107/rcub_technorep_576 .
Grgur, Branimir, Marković, Nenad M., Ross, Philip N.Jr., "Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo alloy" in Journal of the Serbian Chemical Society, 68, no. 3 (2003):191-205,
https://hdl.handle.net/21.15107/rcub_technorep_576 .

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