Приказ основних података о документу

dc.creatorMolina, Ricardo
dc.creatorTeixidó, Josep Maria
dc.creatorKan, Chi-Wai
dc.creatorJovančić, Petar
dc.date.accessioned2023-02-06T14:22:42Z
dc.date.available2023-02-06T14:22:42Z
dc.date.issued2017
dc.identifier.issn1944-8244
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/5823
dc.description.abstractPlasma polymerization using hydrophobic monomers in the gas phase is a well-known technology to generate hydrophobic coatings. However, synthesis of functional hydrophobic coatings using plasma technology in liquids has not yet been accomplished. This work is consequently focused on polymerization of a liquid fluorinated monomer on cotton fabric initiated by atmospheric plasma in a dielectric barrier discharge configuration. Functional hydrophobic coatings on cotton were successfully achieved using in situ atmospheric plasma-initiated polymerization of fluorinated monomer dissolved in ethanol. Gravimetric measurements reveal that the amount of polymer deposited on cotton substrates can be modulated with the concentration of monomer in ethanol solution, and cross-linking reactions occur during plasma polymerization of a fluorinated monomer even without the presence of a cross-linking agent. FTIR and XPS analysis were used to study the chemical composition of hydrophobic coatings and to get insights into the physicochemical processes involved in plasma treatment. SEM analysis reveals that at high monomer concentration, coatings possess a three-dimensional pattern with a characteristic interconnected porous network structure. EDX analysis reveals that plasma polymerization of fluorinated monomers takes place preferentially at the surface of cotton fabric and negligible polymerization takes place inside the cotton fabric. Wetting time measurements confirm the hydrophobicity of cotton coatings obtained although equilibrium moisture content was slightly decreased. Additionally, the abrasion behavior and resistance to washing of plasma-coated cotton has been evaluated.sr
dc.language.isoensr
dc.publisherAmerican Chemical Societysr
dc.relationEuropean Regional Development Funds program (EU-FEDER).sr
dc.relationThe Spanish Ministry of Economy and Competitiveness (Projects MAT2013-40852-R, MAT2013- 42900-P).sr
dc.relationCSIC/ RGC Joint Research Scheme sponsored by the Research Grants Council of Hong Kong and the Spanish National Research Council (Reference No. S-HK007/12).sr
dc.rightsrestrictedAccesssr
dc.sourceACS Applied Materials and Interfacessr
dc.subjectabrasionsr
dc.subjectcottonsr
dc.subjectfluorinated monomersr
dc.subjecthydrophobic coatingssr
dc.subjectplasma in liquidssr
dc.subjectplasma polymerizationsr
dc.titleHydrophobic Coatings on Cotton Obtained by in Situ Plasma Polymerization of a Fluorinated Monomer in Ethanol Solutionssr
dc.typearticlesr
dc.rights.licenseARRsr
dc.citation.epage5521
dc.citation.issue6
dc.citation.rankaM21
dc.citation.spage5513
dc.citation.volume9
dc.identifier.doi10.1021/acsami.6b15812
dc.identifier.scopus2-s2.0-85013105541
dc.identifier.wos000394481800053
dc.type.versionpublishedVersionsr


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Приказ основних података о документу