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Pulverized river shellfish shells as a cheap adsorbent for removing of malathion from water: Examination of the isotherms, kinetics, thermodynamics and optimization of the experimental conditions by the response surface method

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2021
Pulverized_river_shellfish_pub_2021.pdf (1.068Mb)
Authors
Veličković, Zlate S.
Vujičić, Bogdan D.
Stojanović, Vladica N.
Stojisavljević, Predrag N.
Bajić, Zoran J.
Đokić, Veljko R.
Ivanković, Negovan D.
Otrisal, Pavel P.
Article (Published version)
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Abstract
Introduction/purpose: In this study, we investigated the possibility of removing the organophosphorus pesticide malathion from water using a new adsorbent based on the biowaste of river shell shards from the Anodonta Sinadonta woodiane family, a material that accumulates in large quantities as waste on the banks of large rivers. Two adsorbents were tested - mechanically comminuted river shells (MRM) and mechanosynthetic hydroxyapatite from comminuted river shells (RMHAp). Methods: The obtained adsorbents were characterized and tested for the removal of the organophosphorus pesticide malathion from water. In order to predict the optimal adsorption conditions using the Response Surface Method (RSM), the authors investigated the influence of variable factors (adsorption conditions), pH values, adsorbent doses, contact times, and temperatures on the adsorbent capacity. Results: The best adsorption of malathion was achieved at mean pH values between 6.0 and 7.0. The adsorption data for mala...thion at 25, 35, and 45 °C were compared using the Langmuir, Freundlich, DubininRadushkevich (DR), and Temkin isothermal models, as well as pseudofirst order, pseudo-second order and Elovic kinetic models for modeling adsorption kinetics. The maximum Langmuir adsorption capacity for MRM and RMHAp at 25 °C was 46,462 mg g-1 and 78,311 mg g-1 , respectively. Conclusion: The results have showed that malathion adsorption on both adsorbents follows the pseudo-second kinetic model and the Freundlich isothermal model. The thermodynamic parameters indicate the endothermic, feasible, and spontaneous nature of the adsorption process.

Keywords:
removal / adsorbent / kinetics / isotherms / optimization / pesticide / water / river shells
Source:
Vojnotehnički glasnik, 2021, 69, 4, 871-904
Publisher:
  • University of Defence in Belgrade
Funding / projects:
  • The Ministry of Education, Science and Technological Development of the Republic of Serbia (Contract No.: 213-1/21-08-03-2021).

DOI: 10.5937/vojtehg69-32844

ISSN: 0042-8469

[ Google Scholar ]
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6101
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Veličković, Zlate S.
AU  - Vujičić, Bogdan D.
AU  - Stojanović, Vladica N.
AU  - Stojisavljević, Predrag N.
AU  - Bajić, Zoran J.
AU  - Đokić, Veljko R.
AU  - Ivanković, Negovan D.
AU  - Otrisal, Pavel P.
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6101
AB  - Introduction/purpose: In this study, we investigated the possibility of removing the organophosphorus pesticide malathion from water using a new adsorbent based on the biowaste of river shell shards from the Anodonta Sinadonta woodiane family, a material that accumulates in large quantities as waste on the banks of large rivers. Two adsorbents were tested - mechanically comminuted river shells (MRM) and mechanosynthetic hydroxyapatite from comminuted river shells (RMHAp). Methods: The obtained adsorbents were characterized and tested for the removal of the organophosphorus pesticide malathion from water. In order to predict the optimal adsorption conditions using the Response Surface Method (RSM), the authors investigated the influence of variable factors (adsorption conditions), pH values, adsorbent doses, contact times, and temperatures on the adsorbent capacity. Results: The best adsorption of malathion was achieved at mean pH values between 6.0 and 7.0. The adsorption data for malathion at 25, 35, and 45 °C were compared using the Langmuir, Freundlich, DubininRadushkevich (DR), and Temkin isothermal models, as well as pseudofirst order, pseudo-second order and Elovic kinetic models for modeling adsorption kinetics. The maximum Langmuir adsorption capacity for MRM and RMHAp at 25 °C was 46,462 mg g-1 and 78,311 mg g-1 , respectively. Conclusion: The results have showed that malathion adsorption on both adsorbents follows the pseudo-second kinetic model and the Freundlich isothermal model. The thermodynamic parameters indicate the endothermic, feasible, and spontaneous nature of the adsorption process.
PB  - University of Defence in Belgrade
T2  - Vojnotehnički glasnik
T1  - Pulverized river shellfish shells as a cheap adsorbent for removing of malathion from water: Examination of the isotherms, kinetics, thermodynamics and optimization of the experimental conditions by the response surface method
EP  - 904
IS  - 4
SP  - 871
VL  - 69
DO  - 10.5937/vojtehg69-32844
ER  - 
@article{
author = "Veličković, Zlate S. and Vujičić, Bogdan D. and Stojanović, Vladica N. and Stojisavljević, Predrag N. and Bajić, Zoran J. and Đokić, Veljko R. and Ivanković, Negovan D. and Otrisal, Pavel P.",
year = "2021",
abstract = "Introduction/purpose: In this study, we investigated the possibility of removing the organophosphorus pesticide malathion from water using a new adsorbent based on the biowaste of river shell shards from the Anodonta Sinadonta woodiane family, a material that accumulates in large quantities as waste on the banks of large rivers. Two adsorbents were tested - mechanically comminuted river shells (MRM) and mechanosynthetic hydroxyapatite from comminuted river shells (RMHAp). Methods: The obtained adsorbents were characterized and tested for the removal of the organophosphorus pesticide malathion from water. In order to predict the optimal adsorption conditions using the Response Surface Method (RSM), the authors investigated the influence of variable factors (adsorption conditions), pH values, adsorbent doses, contact times, and temperatures on the adsorbent capacity. Results: The best adsorption of malathion was achieved at mean pH values between 6.0 and 7.0. The adsorption data for malathion at 25, 35, and 45 °C were compared using the Langmuir, Freundlich, DubininRadushkevich (DR), and Temkin isothermal models, as well as pseudofirst order, pseudo-second order and Elovic kinetic models for modeling adsorption kinetics. The maximum Langmuir adsorption capacity for MRM and RMHAp at 25 °C was 46,462 mg g-1 and 78,311 mg g-1 , respectively. Conclusion: The results have showed that malathion adsorption on both adsorbents follows the pseudo-second kinetic model and the Freundlich isothermal model. The thermodynamic parameters indicate the endothermic, feasible, and spontaneous nature of the adsorption process.",
publisher = "University of Defence in Belgrade",
journal = "Vojnotehnički glasnik",
title = "Pulverized river shellfish shells as a cheap adsorbent for removing of malathion from water: Examination of the isotherms, kinetics, thermodynamics and optimization of the experimental conditions by the response surface method",
pages = "904-871",
number = "4",
volume = "69",
doi = "10.5937/vojtehg69-32844"
}
Veličković, Z. S., Vujičić, B. D., Stojanović, V. N., Stojisavljević, P. N., Bajić, Z. J., Đokić, V. R., Ivanković, N. D.,& Otrisal, P. P.. (2021). Pulverized river shellfish shells as a cheap adsorbent for removing of malathion from water: Examination of the isotherms, kinetics, thermodynamics and optimization of the experimental conditions by the response surface method. in Vojnotehnički glasnik
University of Defence in Belgrade., 69(4), 871-904.
https://doi.org/10.5937/vojtehg69-32844
Veličković ZS, Vujičić BD, Stojanović VN, Stojisavljević PN, Bajić ZJ, Đokić VR, Ivanković ND, Otrisal PP. Pulverized river shellfish shells as a cheap adsorbent for removing of malathion from water: Examination of the isotherms, kinetics, thermodynamics and optimization of the experimental conditions by the response surface method. in Vojnotehnički glasnik. 2021;69(4):871-904.
doi:10.5937/vojtehg69-32844 .
Veličković, Zlate S., Vujičić, Bogdan D., Stojanović, Vladica N., Stojisavljević, Predrag N., Bajić, Zoran J., Đokić, Veljko R., Ivanković, Negovan D., Otrisal, Pavel P., "Pulverized river shellfish shells as a cheap adsorbent for removing of malathion from water: Examination of the isotherms, kinetics, thermodynamics and optimization of the experimental conditions by the response surface method" in Vojnotehnički glasnik, 69, no. 4 (2021):871-904,
https://doi.org/10.5937/vojtehg69-32844 . .

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