The crystal structure of a cobalt silicoaluminophosphate, CoSAPO-34, is reported. The crystals belong to the rhombohedral R3 space group with unit cell parameters a = 13.797(7) and c = 14.898(7) A. The final R index was 0.055 for 771 independent reflections. The framework structure is very close to that of
natural chabazite but with ordered tetrahedral sites, apparently (Al, Co) and (P, Si). The experimental evidence strongly supports the view that cobalt ions are incorporated into the framework. Each large cavity is occupied by one water molecule and by an isopropylamine molecule. The water 0 atom binds
through weak hydrogen bonds to three 0 atoms of the six-membered ring, whereas the N atom binds in a similar way to the 0 atoms of the eight-membered window.
TY - JOUR
AU - Nardin, G.
AU - Randaccio, L.
AU - Kaucic, V.
AU - Rajic, N.
PY - 1991
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6386
AB - The crystal structure of a cobalt silicoaluminophosphate, CoSAPO-34, is reported. The crystals belong to the rhombohedral R3 space group with unit cell parameters a = 13.797(7) and c = 14.898(7) A. The final R index was 0.055 for 771 independent reflections. The framework structure is very close to that of
natural chabazite but with ordered tetrahedral sites, apparently (Al, Co) and (P, Si). The experimental evidence strongly supports the view that cobalt ions are incorporated into the framework. Each large cavity is occupied by one water molecule and by an isopropylamine molecule. The water 0 atom binds
through weak hydrogen bonds to three 0 atoms of the six-membered ring, whereas the N atom binds in a similar way to the 0 atoms of the eight-membered window.
T2 - Butterworth-Heinemann, Elsevier
T1 - The structure of CoSAPO-34, containing i-propylamine as a template
EP - 194
SP - 192
VL - 11
UR - https://hdl.handle.net/21.15107/rcub_technorep_6386
ER -
@article{
author = "Nardin, G. and Randaccio, L. and Kaucic, V. and Rajic, N.",
year = "1991",
abstract = "The crystal structure of a cobalt silicoaluminophosphate, CoSAPO-34, is reported. The crystals belong to the rhombohedral R3 space group with unit cell parameters a = 13.797(7) and c = 14.898(7) A. The final R index was 0.055 for 771 independent reflections. The framework structure is very close to that of
natural chabazite but with ordered tetrahedral sites, apparently (Al, Co) and (P, Si). The experimental evidence strongly supports the view that cobalt ions are incorporated into the framework. Each large cavity is occupied by one water molecule and by an isopropylamine molecule. The water 0 atom binds
through weak hydrogen bonds to three 0 atoms of the six-membered ring, whereas the N atom binds in a similar way to the 0 atoms of the eight-membered window.",
journal = "Butterworth-Heinemann, Elsevier",
title = "The structure of CoSAPO-34, containing i-propylamine as a template",
pages = "194-192",
volume = "11",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6386"
}
Nardin, G., Randaccio, L., Kaucic, V.,& Rajic, N.. (1991). The structure of CoSAPO-34, containing i-propylamine as a template. in Butterworth-Heinemann, Elsevier, 11, 192-194.
https://hdl.handle.net/21.15107/rcub_technorep_6386
Nardin G, Randaccio L, Kaucic V, Rajic N. The structure of CoSAPO-34, containing i-propylamine as a template. in Butterworth-Heinemann, Elsevier. 1991;11:192-194.
https://hdl.handle.net/21.15107/rcub_technorep_6386 .
Nardin, G., Randaccio, L., Kaucic, V., Rajic, N., "The structure of CoSAPO-34, containing i-propylamine as a template" in Butterworth-Heinemann, Elsevier, 11 (1991):192-194,
https://hdl.handle.net/21.15107/rcub_technorep_6386 .
