Manganese(ll)/phosphate/organic template hydrothermal reactions were investigated with the aim of preparing novel crystalline porous materials. Ethylenediamine, isopropylamine, and piperidine were explored as organics that would be able to organize oxide moieties of Mn(II) and P(V) into a porous MnPO, crystalline lattice. The synthesis in the presence of ethylenediamine yields a product with the double protonated organic entrapped in the void space of the crystal. However, the products obtained in the presence of isopropylamine and piperidine do not contain any organics. It seems that the only role of isopropylamine and piperidine in the crystallization of MnPO material is that of a base. Total removal of the occluded species occurs at around 3OO”C,
after which the manganese phosphate products become X-ray amorphous.
TY - JOUR
AU - Rajić, Nevenka
AU - Ristić, Alenka
AU - Kaučič, Venčeslav
PY - 1996
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6388
AB - Manganese(ll)/phosphate/organic template hydrothermal reactions were investigated with the aim of preparing novel crystalline porous materials. Ethylenediamine, isopropylamine, and piperidine were explored as organics that would be able to organize oxide moieties of Mn(II) and P(V) into a porous MnPO, crystalline lattice. The synthesis in the presence of ethylenediamine yields a product with the double protonated organic entrapped in the void space of the crystal. However, the products obtained in the presence of isopropylamine and piperidine do not contain any organics. It seems that the only role of isopropylamine and piperidine in the crystallization of MnPO material is that of a base. Total removal of the occluded species occurs at around 3OO”C,
after which the manganese phosphate products become X-ray amorphous.
PB - Elsevier Inc.
T2 - Zeolites
T1 - On the possibility of the preparation open framework manganese phosphate
EP - 309
IS - 3
SP - 304
VL - 17
DO - 10.1016/0144-2449(96)00027-9
UR - https://hdl.handle.net/21.15107/rcub_technorep_6388
ER -
@article{
author = "Rajić, Nevenka and Ristić, Alenka and Kaučič, Venčeslav",
year = "1996",
abstract = "Manganese(ll)/phosphate/organic template hydrothermal reactions were investigated with the aim of preparing novel crystalline porous materials. Ethylenediamine, isopropylamine, and piperidine were explored as organics that would be able to organize oxide moieties of Mn(II) and P(V) into a porous MnPO, crystalline lattice. The synthesis in the presence of ethylenediamine yields a product with the double protonated organic entrapped in the void space of the crystal. However, the products obtained in the presence of isopropylamine and piperidine do not contain any organics. It seems that the only role of isopropylamine and piperidine in the crystallization of MnPO material is that of a base. Total removal of the occluded species occurs at around 3OO”C,
after which the manganese phosphate products become X-ray amorphous.",
publisher = "Elsevier Inc.",
journal = "Zeolites",
title = "On the possibility of the preparation open framework manganese phosphate",
pages = "309-304",
number = "3",
volume = "17",
doi = "10.1016/0144-2449(96)00027-9",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6388"
}
Rajić, N., Ristić, A.,& Kaučič, V.. (1996). On the possibility of the preparation open framework manganese phosphate. in Zeolites
Elsevier Inc.., 17(3), 304-309.
https://doi.org/10.1016/0144-2449(96)00027-9
https://hdl.handle.net/21.15107/rcub_technorep_6388
Rajić N, Ristić A, Kaučič V. On the possibility of the preparation open framework manganese phosphate. in Zeolites. 1996;17(3):304-309.
doi:10.1016/0144-2449(96)00027-9
https://hdl.handle.net/21.15107/rcub_technorep_6388 .
Rajić, Nevenka, Ristić, Alenka, Kaučič, Venčeslav, "On the possibility of the preparation open framework manganese phosphate" in Zeolites, 17, no. 3 (1996):304-309,
https://doi.org/10.1016/0144-2449(96)00027-9 .,
https://hdl.handle.net/21.15107/rcub_technorep_6388 .
