The dehydration behavior of two synthetic, unsubstituted and cobalt-substituted, zincophos phates (one a sodalite analog and the other a new, hexagonal phase) was studied by TG/DTG and DSC. TG/DTG curves of the sodalite phases were very similar, exhibiting only one major weight loss that shifted to higher temperatures with increased amount of cobalt substitution. The profiles of the corresponding DSC curves, however, differed considerably among themselves.
TG/DTG curves of hexagonal phases showed a more complex, multi-step dehydration behavior; the corresponding DSC curves also exhibited multiple endotherms. An explanation of these phenomena is given in terms of the specific arrangement of water molecules within a particular zincophosphate framework.
TY - JOUR
AU - Rajić, Nevenka
AU - Gabrovšek, Roman
AU - Kaučič, Venčeslav
PY - 1996
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6389
AB - The dehydration behavior of two synthetic, unsubstituted and cobalt-substituted, zincophos phates (one a sodalite analog and the other a new, hexagonal phase) was studied by TG/DTG and DSC. TG/DTG curves of the sodalite phases were very similar, exhibiting only one major weight loss that shifted to higher temperatures with increased amount of cobalt substitution. The profiles of the corresponding DSC curves, however, differed considerably among themselves.
TG/DTG curves of hexagonal phases showed a more complex, multi-step dehydration behavior; the corresponding DSC curves also exhibited multiple endotherms. An explanation of these phenomena is given in terms of the specific arrangement of water molecules within a particular zincophosphate framework.
PB - Elsevier
T2 - Thermochimica Acta
T1 - Dehydration behavior of some microporous zincophosphates
EP - 164
SP - 157
VL - 278
UR - https://hdl.handle.net/21.15107/rcub_technorep_6389
ER -
@article{
author = "Rajić, Nevenka and Gabrovšek, Roman and Kaučič, Venčeslav",
year = "1996",
abstract = "The dehydration behavior of two synthetic, unsubstituted and cobalt-substituted, zincophos phates (one a sodalite analog and the other a new, hexagonal phase) was studied by TG/DTG and DSC. TG/DTG curves of the sodalite phases were very similar, exhibiting only one major weight loss that shifted to higher temperatures with increased amount of cobalt substitution. The profiles of the corresponding DSC curves, however, differed considerably among themselves.
TG/DTG curves of hexagonal phases showed a more complex, multi-step dehydration behavior; the corresponding DSC curves also exhibited multiple endotherms. An explanation of these phenomena is given in terms of the specific arrangement of water molecules within a particular zincophosphate framework.",
publisher = "Elsevier",
journal = "Thermochimica Acta",
title = "Dehydration behavior of some microporous zincophosphates",
pages = "164-157",
volume = "278",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6389"
}
Rajić, N., Gabrovšek, R.,& Kaučič, V.. (1996). Dehydration behavior of some microporous zincophosphates. in Thermochimica Acta
Elsevier., 278, 157-164.
https://hdl.handle.net/21.15107/rcub_technorep_6389
Rajić N, Gabrovšek R, Kaučič V. Dehydration behavior of some microporous zincophosphates. in Thermochimica Acta. 1996;278:157-164.
https://hdl.handle.net/21.15107/rcub_technorep_6389 .
Rajić, Nevenka, Gabrovšek, Roman, Kaučič, Venčeslav, "Dehydration behavior of some microporous zincophosphates" in Thermochimica Acta, 278 (1996):157-164,
https://hdl.handle.net/21.15107/rcub_technorep_6389 .
