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A cobalt(II) complex with ethylenediamine inside zeolite A
dc.creator | Rajić, Nevenka Z. | |
dc.creator | Stojaković, Djordje R. | |
dc.date.accessioned | 2023-05-23T09:19:37Z | |
dc.date.available | 2023-05-23T09:19:37Z | |
dc.date.issued | 1994 | |
dc.identifier.issn | 1318-0207 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6396 | |
dc.description.abstract | Reaction of the partially dehydrated cobalt(II)-exchanged zeolite A (Co-A) with ethylenediamine (en) at 130 C in an autoclave yields after 24 h a product (Coen-A) in which entire Co(II) content (tetrahedrally coordinated in the partially dehydrated Co-A) is present in the form of the Co(en)3(2+) ions. Steric factors require the Co(en)3(2+) ions to be substituted only in the larger cages of zeolite A (alfa-cages), implying that the conversion of Co-A into Coen-A is accompanied by a migration of Co2+ ions initially located in the smaller cages (beta-cages) into alfa-cages. The Co/en molar ratio in Coen-A is 1:5.6, so that a fraction of en is also present in a noncoordinated form. IR spectral data suggest that the coordinated en adopts to the gauche conformation. TG analysis shows that the thermal decomposition of Coen-A occurs in four steps, such that water is lost first, followed by the loss of en. | sr |
dc.language.iso | en | sr |
dc.publisher | Slovenian Chemical Society | sr |
dc.relation | Research Fund of Serbia | sr |
dc.rights | openAccess | sr |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Acta Chimica Slovenica | sr |
dc.title | A cobalt(II) complex with ethylenediamine inside zeolite A | sr |
dc.type | article | sr |
dc.rights.license | BY | sr |
dc.citation.epage | 304 | |
dc.citation.issue | 3 | |
dc.citation.spage | 295 | |
dc.citation.volume | 41 | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_technorep_6396 | |
dc.type.version | publishedVersion | sr |
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