Two different open-framework cobalt-zincophosphate phases crystallise from the same reaction mixture at ambient conditions depending on the preparative procedure. One of them is a sodalite analogue containing up 70 8 wt.% of incorporated cobalt(II), in proportion to a molar fraction of cobalt(II) component in the reaction mixture. The other is anovel hexagonal phase with a three-dimensional tetrahedral framework structure containing one-dimensional six-ring channels. A helix built up of sodium cations and water molecules has been found inside the channel.
Source:
Synthesis of Porous Materials - Zeolites, Clays, and Nanostructures, 1997, 69, 233-242
TY - CHAP
AU - Rajić, Nevenka
AU - Zabukovec Logar, Nataša
AU - Meden, Anton
AU - Kaučič, Venčeslav
PY - 1997
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6402
AB - Two different open-framework cobalt-zincophosphate phases crystallise from the same reaction mixture at ambient conditions depending on the preparative procedure. One of them is a sodalite analogue containing up 70 8 wt.% of incorporated cobalt(II), in proportion to a molar fraction of cobalt(II) component in the reaction mixture. The other is anovel hexagonal phase with a three-dimensional tetrahedral framework structure containing one-dimensional six-ring channels. A helix built up of sodium cations and water molecules has been found inside the channel.
PB - Marcel Dekker, Inc.
T2 - Synthesis of Porous Materials - Zeolites, Clays, and Nanostructures
T1 - Preparation of Two Cobalt-Substituted Zincophosphate Molecular Sieves
EP - 242
SP - 233
VL - 69
UR - https://hdl.handle.net/21.15107/rcub_technorep_6402
ER -
@inbook{
author = "Rajić, Nevenka and Zabukovec Logar, Nataša and Meden, Anton and Kaučič, Venčeslav",
year = "1997",
abstract = "Two different open-framework cobalt-zincophosphate phases crystallise from the same reaction mixture at ambient conditions depending on the preparative procedure. One of them is a sodalite analogue containing up 70 8 wt.% of incorporated cobalt(II), in proportion to a molar fraction of cobalt(II) component in the reaction mixture. The other is anovel hexagonal phase with a three-dimensional tetrahedral framework structure containing one-dimensional six-ring channels. A helix built up of sodium cations and water molecules has been found inside the channel.",
publisher = "Marcel Dekker, Inc.",
journal = "Synthesis of Porous Materials - Zeolites, Clays, and Nanostructures",
booktitle = "Preparation of Two Cobalt-Substituted Zincophosphate Molecular Sieves",
pages = "242-233",
volume = "69",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6402"
}
Rajić, N., Zabukovec Logar, N., Meden, A.,& Kaučič, V.. (1997). Preparation of Two Cobalt-Substituted Zincophosphate Molecular Sieves. in Synthesis of Porous Materials - Zeolites, Clays, and Nanostructures
Marcel Dekker, Inc.., 69, 233-242.
https://hdl.handle.net/21.15107/rcub_technorep_6402
Rajić N, Zabukovec Logar N, Meden A, Kaučič V. Preparation of Two Cobalt-Substituted Zincophosphate Molecular Sieves. in Synthesis of Porous Materials - Zeolites, Clays, and Nanostructures. 1997;69:233-242.
https://hdl.handle.net/21.15107/rcub_technorep_6402 .
Rajić, Nevenka, Zabukovec Logar, Nataša, Meden, Anton, Kaučič, Venčeslav, "Preparation of Two Cobalt-Substituted Zincophosphate Molecular Sieves" in Synthesis of Porous Materials - Zeolites, Clays, and Nanostructures, 69 (1997):233-242,
https://hdl.handle.net/21.15107/rcub_technorep_6402 .
